In this review, the recent applications of a variety of chiral imino-containing ligands classified
by different types of metal-catalyzed asymmetric reactions are summarized. The progress …

The Nazarov electrocyclization reaction is a convenient, widely used method for construction
of cyclopentenones. In the past few decades, catalytic asymmetric versions of the reaction …

Highly substituted 2‐cyclopentenones were stereospecifically and regioselectively
constructed with high catalytic efficiency through Lewis‐acid catalyzed decarboxylative …

In this report, we describe a halo-Prins/aryl halo-Nazarov cyclization strategy that employs
readily available starting materials, inexpensive reagents, and convenient reaction …

Enantioselective control of the chirality of a tertiary α-carbon in the products of a Nazarov
cyclization of enones is challenging because the reaction involves an enantioselective …

The application of Lewis acidic chiral‐at‐metal complexes of iridium (III) and rhodium (III) as
catalysts for the asymmetric polarized Nazarov cyclization of dihydropyran‐and indole …

The photosynthetic tetrapyrroles and their catabolic products (phyllobilins) share similar
structural features in the southern rim encompassing rings C–E with variation in the degree …

An efficient chiral Brønsted acid-catalyzed enantioselective dehydrative Nazarov-type
electrocyclization (DNE) of electron-rich aryl-and 2-thienyl-β-amino-2-en-1-ols is described …

We report an enantioselective Nazarov cyclization catalyzed by chiral hydrogen‐bond‐
donors in concert with silyl Lewis acids. The developed transformation provides access to tri …

Nazarov cyclization is an important and versatile method for the synthesis of five‐membered
carbocycles, and extensive studies have been conducted to optimize the reaction. Among …