Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Plastic pollution: a material problem?

JM Millican, S Agarwal - Macromolecules, 2021 - ACS Publications
The field of polymer science recently celebrated its 100th anniversary. The excellent
material properties of a wide range of plastics (generally used as a synonym for polymers) …

Current Standing on Radical Ring‐Opening Polymerizations of Cyclic Ketene Acetals as Homopolymers and Copolymers with one another

Y Deng, F Mehner, J Gaitzsch - Macromolecular Rapid …, 2023 - Wiley Online Library
Radical Ring‐opening polymerization (RROP) of cyclic ketene acetals (CKAs) emerges to
be a valuable polymerization technique. In attracting more attention, RROP has seen a new …

100th anniversary of macromolecular science viewpoint: Degradable polymers from radical ring-opening polymerization: Latest advances, new directions, and …

T Pesenti, J Nicolas - ACS Macro Letters, 2020 - ACS Publications
Radical ring-opening polymerization (rROP) allows facile incorporation of labile groups (eg,
ester) into the main chain of vinyl polymers to obtain (bio) degradable materials. rROP has …

Degradable vinyl random copolymers via photocontrolled radical ring‐opening cascade copolymerization

W Wang, Z Zhou, D Sathe, X Tang… - Angewandte Chemie …, 2022 - Wiley Online Library
Degradable vinyl polymers by radical ring‐opening polymerization are promising solutions
to the challenges caused by non‐degradable vinyl plastics. However, achieving even …

Degradable polystyrene via the cleavable comonomer approach

N Gil, B Caron, D Siri, J Roche, S Hadiouch… - …, 2022 - ACS Publications
Polystyrene (PS) is a major commodity polymer widely used in various applications ranging
from packaging to insulation thanks to its low cost, high stiffness, and transparency as well …

A Strategy for Controlling the Polymerizations of Thiyl Radical Propagation by RAFT Agents

S Zhang, Y Wang, H Huang… - Angewandte Chemie …, 2023 - Wiley Online Library
The ability to extend the polymerizations of thiyl radical propagation to be regulated by
existing controlled methods would be highly desirable, yet remained very challenging to …

Development of an Efficient Thionolactone for Radical Ring-Opening Polymerization by a Combined Theoretical/Experimental Approach

B Luzel, N Gil, P Désirée, J Monot… - Journal of the …, 2023 - ACS Publications
The environmental impact of plastic waste has been a real problem for the past decades.
The incorporation of cleavable bonds in the polymer backbone is a solution to making a …

Poly (ε-caprolactone)-based graft copolymers: synthesis methods and applications in the biomedical field: a review

J Coudane, B Nottelet, J Mouton, X Garric… - Molecules, 2022 - mdpi.com
Synthetic biopolymers are attractive alternatives to biobased polymers, especially because
they rarely induce an immune response in a living organism. Poly ε-caprolactone (PCL) is a …

Multi-scale reactive extrusion modelling approaches to design polymer synthesis, modification and mechanical recycling

K De Smit, T Wieme, YW Marien… - Reaction Chemistry & …, 2022 - pubs.rsc.org
Reactive extrusion (REX) is an important processing and production technique with
applications in the field of polymer synthesis, modification and recycling. A full REX design …