Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F Jin - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Current status and future developments of endohedral metallofullerenes

X Lu, L Feng, T Akasaka, S Nagase - Chemical Society Reviews, 2012 - pubs.rsc.org
Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …

Endohedral fullerenes for organic photovoltaic devices

RB Ross, CM Cardona, DM Guldi… - Nature materials, 2009 - nature.com
So far, one of the fundamental limitations of organic photovoltaic (OPV) device power
conversion efficiencies (PCEs) has been the low voltage output caused by a molecular …

Chemical, electrochemical, and structural properties of endohedral metallofullerenes

MN Chaur, F Melin, AL Ortiz… - Angewandte Chemie …, 2009 - Wiley Online Library
Ever since the first experimental evidence of the existence of endohedral metallofullerenes
(EMFs) was obtained, the search for carbon cages with encapsulated metals and small …

The nano-forms of carbon

JL Delgado, MÁ Herranz, N Martin - Journal of Materials Chemistry, 2008 - pubs.rsc.org
Since the discovery of C60fullerene, carbon-based nanostructures have become one of the
hottest research topics in science. During the past decade research efforts have mainly been …

Chemistry of endohedral metallofullerenes: the role of metals

X Lu, T Akasaka, S Nagase - Chemical Communications, 2011 - pubs.rsc.org
Recent breakthroughs achieved in the chemical functionalization of endohedral
metallofullerenes (EMFs), especially single crystallographic X-ray characterizations of their …

Trimetallic nitride template endohedral metallofullerenes: discovery, structural characterization, reactivity, and applications

J Zhang, S Stevenson, HC Dorn - Accounts of chemical research, 2013 - ACS Publications
Shortly after the discovery of the carbon fullerene allotrope, C60, researchers recognized
that the hollow spheroidal shape could accommodate metal atoms, or clusters, which quickly …

Structurally Defined Water‐Soluble Metallofullerene Derivatives towards Biomedical Applications

Y Li, R Biswas, WP Kopcha, T Dubroca… - Angewandte …, 2023 - Wiley Online Library
Endohedral metallofullerenes (EMFs) are excellent carriers of rare‐earth element (REE)
ions in biomedical applications because they preclude the release of toxic metal ions …

Carbene additions to fullerenes

M Yamada, T Akasaka, S Nagase - Chemical Reviews, 2013 - ACS Publications
Carbon is the most prominent element of state-of-the-art nanoscience. Kroto, Curl, and
Smalley were awarded the Nobel Prize in Chemistry in 1996 for discovery of fullerenes. 1− 4 …