Charge transfer processes in OPV materials as revealed by EPR spectroscopy

J Niklas, OG Poluektov - Advanced Energy Materials, 2017 - Wiley Online Library
Understanding charge separation and charge transport at a molecular level is crucial for
improving the efficiency of organic photovoltaic (OPV) cells. Under illumination of Bulk …

Electronic Structure and Properties of Organic Bulk‐Heterojunction Interfaces

RA Street - Advanced Materials, 2016 - Wiley Online Library
The electronic structure and physical mechanisms of carrier generation and transport in the
organic bulk heterojunction are reviewed. The electronic structure describes the bands and …

Computational tools for the simulation and analysis of spin-polarized EPR spectra

CE Tait, MD Krzyaniak, S Stoll - Journal of Magnetic Resonance, 2023 - Elsevier
The EPR spectra of paramagnetic species induced by photoexcitation typically exhibit
enhanced absorptive and emissive features resulting from sublevel populations that differ …

Photovoltaic function and exciton/charge transfer dynamics in a highly efficient semiconducting copolymer

JM Szarko, BS Rolczynski, SJ Lou, T Xu… - Advanced Functional …, 2014 - Wiley Online Library
Exciton dissociation is a key step for the light energy conversion to electricity in organic
photovoltaic (OPV) devices. Here, excitonic dissociation pathways in the high‐performance …

Geminate and nongeminate pathways for triplet exciton formation in organic solar cells

A Privitera, J Grüne, A Karki, WK Myers… - Advanced Energy …, 2022 - Wiley Online Library
Organic solar cells (OSCs) have recently shown a rapid improvement in their performance,
bringing power conversion efficiencies to above 18%. However, the open‐circuit voltage of …

[PDF][PDF] On the efficiency of charge transfer state splitting in polymer: fullerene solar cells

S Albrecht, K Vandewal, JR Tumbleston… - Advanced …, 2014 - academia.edu
Steve Albrecht, Koen Vandewal,* John R. Tumbleston, Florian SU Fischer, Jessica D.
Douglas, Jean MJ Fréchet, Sabine Ludwigs, Harald Ade, Alberto Salleo, and Dieter Neher …

Spin-enhanced organic bulk heterojunction photovoltaic solar cells

Y Zhang, TP Basel, BR Gautam, X Yang… - Nature …, 2012 - nature.com
Recently, much effort has been devoted to improve the efficiency of organic photovoltaic
solar cells based on blends of donors and acceptors molecules in bulk heterojunction …

Structure–function relationship of organic semiconductors: detailed insights from time-resolved EPR spectroscopy

T Biskup - Frontiers in Chemistry, 2019 - frontiersin.org
Organic photovoltaics (OPV) is a promising technology to account for the increasing demand
for energy in form of electricity. Whereas the last decades have seen tremendous progress …

Transient epr

S Weber - EPR Spectroscopy: Fundamentals and Methods, 2018 - books.google.com
Transient EPR (trEPR) spectroscopy is a time-resolved detection technique that has been
pioneered by Soon Sam Kim and Samuel I. Weissman in the late 1970s. 1, 2 It has proven to …

Charge separation in PCPDTBT: PCBM blends from an EPR perspective

F Kraffert, R Steyrleuthner, S Albrecht… - The Journal of …, 2014 - ACS Publications
Using time-resolved electron paramagnetic resonance (EPR) spectroscopy in conjunction
with optical excitation we study charge separation in conjugated polymers blended with [6 …