Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

Palladium catalyzed C–C and C–N bond forming reactions: an update on the synthesis of pharmaceuticals from 2015–2020

J Rayadurgam, S Sana, M Sasikumar… - Organic Chemistry …, 2021 - pubs.rsc.org
Some of the most prominent and promising catalysts in organic synthesis for the requisite
construction of C–C and C–N bonds are palladium (Pd) catalysts, which play a pivotal role in …

Electrochemically enabled, nickel-catalyzed dehydroxylative cross-coupling of alcohols with aryl halides

Z Li, W Sun, X Wang, L Li, Y Zhang… - Journal of the American …, 2021 - ACS Publications
As alcohols are ubiquitous throughout chemical science, this functional group represents a
highly attractive starting material for forging new C–C bonds. Here, we demonstrate that the …

Direct α-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols using Amberlyst-15/ionic liquid as an efficient catalytic system

KV Wagh, BM Bhanage - ACS Sustainable Chemistry & …, 2016 - ACS Publications
The direct α-alkylation of acetophenones with benzhydrols as well as 1-phenylethanols
using Amberlyst-15/[Bmim][PF6] ionic liquid as an affordable catalytic system has been …

Noncovalent interactions in metal complex catalysis

KT Mahmudov, AV Gurbanov, FI Guseinov… - Coordination Chemistry …, 2019 - Elsevier
Metal complex catalysis, in which coordination compounds are designed as catalysts for
chemical transformations employing noncovalent interactions, is emerging as a powerful …

Oxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as a Nucleophilic CF3 Source

L Chu, FL Qing - Accounts of chemical research, 2014 - ACS Publications
Conspectus The trifluoromethyl group is widely prevalent in many pharmaceuticals and
agrochemicals because its incorporation into drug candidates could enhance chemical and …

Dynamic kinetic cross-electrophile arylation of benzyl alcohols by nickel catalysis

P Guo, K Wang, WJ Jin, H Xie, L Qi… - Journal of the …, 2020 - ACS Publications
Catalytic transformation of alcohols via metal-catalyzed cross-coupling reactions is very
important, but it typically relies on a multistep procedure. We here report a dynamic kinetic …

Electrosynthetic C− O bond activation in alcohols and alcohol derivatives

P Villo, A Shatskiy, MD Kärkäs… - Angewandte Chemie …, 2023 - Wiley Online Library
Alcohols and their derivatives are ubiquitous and versatile motifs in organic synthesis.
Deoxygenative transformations of these compounds are often challenging due to the …

Contemporary carbocation chemistry: applications in organic synthesis

RR Naredla, DA Klumpp - Chemical reviews, 2013 - ACS Publications
Contemporary Carbocation Chemistry: Applications in Organic Synthesis | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol

S Zhang, M Vayer, F Noel, VD Vuković, A Golushko… - Chem, 2021 - cell.com
Alcohols and epoxides are arguably ideal electrophiles for the Friedel-Crafts alkylation,
since they are widely available, require no pre-activation, and produce no stoichiometric …