Dearomatization reactions provide rapid access to structurally complex three-dimensional
molecules from simple aromatic compounds. Plenty of reports have demonstrated their …

Dearomatisation reactions of (hetero) arenes have been widely employed as efficient
methods to obtain highly substituted saturated cyclic compounds for over a century. In recent …

Prenylated and reverse-prenylated indolines are privileged scaffolds in numerous naturally
occurring indole alkaloids with a broad spectrum of important biological properties …

The rapid preparation of complex three‐dimensional (3D) heterocyclic scaffolds is a key
challenge in modern medicinal chemistry. Despite the increased probability of clinical …

Reactions that lead to destruction of aromatic ring systems often require harsh conditions
and, thus, take place with poor selectivities. Selective partial dearomatization of fused …

Disclosed here is a visible-light photoredox-catalyzed intermolecular sequential α-
aminomethyl/carboxylative dearomatization of indoles with CO2 and α-aminoalkyl radical …

We report herein a convenient and scalable dearomative hydroacylation reaction of indoles.
Employing readily available aldehydes as the acyl source and TBADT as an inexpensive …

Herein, we describe a methodology to construct polycyclic pyrrolophenanthridones with an
(amino) alkyl side chain that involves visible-light-induced decarboxylative radical addition …

A facile approach toward 3-(o-aminophenyl) pyrroles was developed by remodeling of N-
sulfonyl-3-acyl indoles with N-phenylglycines under photoredox catalysis. This strategy …

A protocol for trans-hydroboration of indole derivatives using heterogeneous photocatalysis
with NHC-borane has been developed, addressing a persistent challenge in organic …