Cross-coupling catalysts typically react and unite functionally distinct partners via sequential
inner-sphere elementary steps: coordination, migratory insertion, reductive elimination, etc …

The regiocontrolled functionalization of 1, 3-dienes has become a powerful tool for divergent
synthesis, yet it remains a long-standing challenge for aliphatic substrates. Herein, we report …

The copper‐catalyzed highly selective protoboration of CF3‐containing conjugated diene
with proton source and B2Pin2 has been developed. This chemistry could suppress the well …

The protoboration of conjugated diene is a kind of important strategy for the synthesis of
allylic borides and homo-allylic borides, because of mild reaction conditions and wide …

An efficient cobalt-catalyzed geometrical isomerization of 1, 3-dienes is described. In the
combination of a CoCl2 precatalyst with an amido-diphosphine-oxazoline ligand, the …

An efficient nickel‐catalyzed regioselective hydroarylation of 1, 3‐dienes with aryl halides
and a silane has been developed, affording a range of allylic arenes in good to excellent …

A practical nickel-catalyzed highly selective alkenylboration of alkenylarenes has been
developed. Under mild reaction conditions, a series of structurally interesting homoallylic …

Merging the stereoisomeric mixture of substrate into a single product through stereospecific
transformation is a challenging but higher‐order synthetic strategy, which perfectly meets the …

An efficient iron-catalyzed hydroarylation of 1, 3-dienes with indoles has been developed for
the first time. This protocol involves the use of the green and inexpensive Earth-abundant …

摘要共轭双烯的硼化质子化反应由于反应条件温和以及官能团兼容性广泛,
目前已经成为合成烯丙基硼化物以及高烯丙基硼化物的重要方法之一. 随着多个课题组在本领域 …