Recent advances in paramagnetic-TM-substituted polyoxometalates (TM= Mn, Fe, Co, Ni, Cu)

ST Zheng, GY Yang - Chemical Society Reviews, 2012 - pubs.rsc.org
During the past decade, research into transition-metal-substituted polyoxometalate self-
assembly has been greatly developed. This review summarizes the conventional solution …

Metal-catalyzed epoxidations of alkenes with hydrogen peroxide

BS Lane, K Burgess - Chemical reviews, 2003 - ACS Publications
Hydrogen peroxide is probably the best terminal oxidant after dioxygen with respect to
environmental and economic considerations. 1-4 Indeed, in certain circumstances, it is …

Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates

N Mizuno, K Yamaguchi, K Kamata - Coordination chemistry reviews, 2005 - Elsevier
Epoxides are an important class of industrial chemicals that have been used as chemical
intermediates. Catalytic epoxidation of olefins affords an interesting technology for their …

Polyoxometalates: Fascinating structures, unique magnetic properties

U Kortz, A Mueller, J van Slageren, J Schnack… - Coordination Chemistry …, 2009 - Elsevier
We report on several discrete molecular transition metal-and lanthanide-containing polyoxo-
tungstates and-molybdates with a focus on their magnetic properties. The polyanions …

Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant

G Grigoropoulou, JH Clark, JA Elings - Green chemistry, 2003 - pubs.rsc.org
This paper reviews recent developments on the epoxidation of alkenes using hydrogen
peroxide as an environmentally friendly oxidant. The activation of hydrogen peroxide takes …

Catalytic transformations of the major terpene feedstocks

KAD Swift - Topics in Catalysis, 2004 - Springer
A review covering some of the key catalytic transformations of the major monoterpene
feedstocks. Monoterpenes are key ingredients in the flavor and fragrance industry, with α …

Manganese-catalyzed epoxidations of alkenes in bicarbonate solutions

BS Lane, M Vogt, VJ DeRose… - Journal of the American …, 2002 - ACS Publications
This paper describes a method, discovered and refined by parallel screening, for the
epoxidation of alkenes. It uses hydrogen peroxide as the terminal oxidant, is promoted by …

Fabricating a functionalized polyoxometalate with ZIF-8: A composite material for water oxidation in a wide pH range

S Mulkapuri, A Ravi, SK Das - Chemistry of Materials, 2022 - ACS Publications
Designing an efficient oxygen evolution reaction (OER) electrocatalyst is a challenging task
because molecular oxygen is essential to sustain life. Herein, we have synthesized and …

Alkali‐Metal‐Controlled Self‐Assembly of Crown‐Shaped Ring Complexes of Lanthanide/[α‐AsW9O33] 9−:[K⊂{Eu (H2O) 2 (α‐AsW9O33)} 6] 35− and [Cs⊂{Eu (H2O …

K Fukaya, T Yamase - Angewandte Chemie, 2003 - Wiley Online Library
{Ce16W148}[5] can be constructed through the coordination of Ln3+ ions by the outer
oxygen atoms of polyoxometalate ligands. The modular construction of these analogues …

Electrochemical Catalysis of Styrene Epoxidation with Films of MnO2 Nanoparticles and H2O2

L Espinal, SL Suib, JF Rusling - Journal of the American Chemical …, 2004 - ACS Publications
Films of polyions and octahedral layered manganese oxide (OL-1) nanoparticles on carbon
electrodes made by layer-by-layer alternate electrostatic adsorption were active for …