Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Transition metal-catalyzed organic reactions under visible light: recent developments and future perspectives

WM Cheng, R Shang - ACS Catalysis, 2020 - ACS Publications
The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

C–H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals

S Sarkar, KPS Cheung, V Gevorgyan - Chemical Science, 2020 - pubs.rsc.org
Selective functionalization of ubiquitous unactivated C–H bonds is a continuous quest for
synthetic organic chemists. In addition to transition metal catalysis, which typically operates …

Ketones from aldehydes via alkyl C(sp3)−H functionalization under photoredox cooperative NHC/palladium catalysis

HY Wang, XH Wang, BA Zhou, CL Zhang… - Nature …, 2023 - nature.com
Direct synthesis of ketones from aldehydes features high atom-and step-economy. Yet, the
coupling of aldehydes with unactivated alkyl C (sp3)-H remains challenging. Herein, we …

Site-selective acceptorless dehydrogenation of aliphatics enabled by organophotoredox/cobalt dual catalysis

MJ Zhou, L Zhang, G Liu, C Xu… - Journal of the American …, 2021 - ACS Publications
The value of catalytic dehydrogenation of aliphatics (CDA) in organic synthesis has
remained largely underexplored. Known homogeneous CDA systems often require the use …

Merging photoinduced iron-catalyzed decarboxylation with copper catalysis for C–N and C–C couplings

N Xiong, Y Li, R Zeng - ACS Catalysis, 2023 - ACS Publications
We report a photoinduced iron/copper dual-catalytic strategy for the radical decarboxylation
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …

Merging of Light/Dark Palladium Catalytic Cycles Enables Multicomponent Tandem Alkyl Heck/Tsuji–Trost Homologative Amination Reaction toward Allylic Amines

N Kvasovs, J Fang, F Kliuev… - Journal of the American …, 2023 - ACS Publications
A visible light-induced palladium-catalyzed homologative three-component synthesis of
allylic amines has been developed. This protocol proceeds via a unique mechanism …

Electrochemical Desaturative β‐Acylation of Cyclic N‐Aryl Amines

T Feng, S Wang, Y Liu, S Liu, Y Qiu - Angewandte Chemie, 2022 - Wiley Online Library
Herein, we disclose a straightforward, robust, and simple route to access β‐substituted
desaturated cyclic amines via an electrochemically driven desaturative β‐functionalization of …

Catalysis with palladium complexes photoexcited by visible light

P Chuentragool, D Kurandina… - Angewandte Chemie …, 2019 - Wiley Online Library
Palladium catalysis induced by visible light is an emerging field of catalysis. In contrast to
classical reactions catalyzed by Pd complexes in the ground state, which mostly proceed …