Degradation mechanisms of polycaprolactone in the context of chemistry, geometry and environment

M Bartnikowski, TR Dargaville, S Ivanovski… - Progress in Polymer …, 2019 - Elsevier
Polycaprolactone (PCL) is a biodegradable polymer that is widely utilized for biomedical
applications, as well as for environmentally sustainable packaging. The mechanisms driving …

PCL-based composite scaffold matrices for tissue engineering applications

N Siddiqui, S Asawa, B Birru, R Baadhe, S Rao - Molecular biotechnology, 2018 - Springer
Biomaterial-based scaffolds are important cues in tissue engineering (TE) applications.
Recent advances in TE have led to the development of suitable scaffold architecture for …

Plastic pollution: a material problem?

JM Millican, S Agarwal - Macromolecules, 2021 - ACS Publications
The field of polymer science recently celebrated its 100th anniversary. The excellent
material properties of a wide range of plastics (generally used as a synonym for polymers) …

Photocatalytic direct decarboxylation of carboxylic acids to derivatize or degrade polymers

A Adili, AB Korpusik, D Seidel… - Angewandte Chemie …, 2022 - Wiley Online Library
Visible light‐mediated direct decarboxylation of carboxylic acids with an acridine
photocatalyst is a convenient and powerful method to generate carbon‐centered radicals in …

Dynamic surface antifouling: mechanism and systems

Q Xie, J Pan, C Ma, G Zhang - Soft Matter, 2019 - pubs.rsc.org
Marine biofouling is a global problem today. High efficiency and eco-friendly antifouling
systems are in pressing need. In recent years, we have proposed the concept of dynamic …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Synthesis, properties and biomedical applications of hydrolytically degradable materials based on aliphatic polyesters and polycarbonates

RP Brannigan, AP Dove - Biomaterials science, 2017 - pubs.rsc.org
Polyester-based polymers represent excellent candidates in synthetic biodegradable and
bioabsorbable materials for medical applications owing to their tailorable properties. The …

Radical ring-opening polymerization: Scope, limitations, and application to (bio) degradable materials

A Tardy, J Nicolas, D Gigmes, C Lefay… - Chemical …, 2017 - ACS Publications
Cyclic monomers bearing either vinyl or exomethylene groups have the ability to be
polymerized through a radical pathway via a ring-opening mechanism (addition …

100th anniversary of macromolecular science viewpoint: Degradable polymers from radical ring-opening polymerization: Latest advances, new directions, and …

T Pesenti, J Nicolas - ACS Macro Letters, 2020 - ACS Publications
Radical ring-opening polymerization (rROP) allows facile incorporation of labile groups (eg,
ester) into the main chain of vinyl polymers to obtain (bio) degradable materials. rROP has …

Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds

P Shieh, MR Hill, W Zhang, SL Kristufek… - Chemical …, 2021 - ACS Publications
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …