Recent advances in computational actinoid chemistry
D Wang, WF van Gunsteren, Z Chai - Chemical Society Reviews, 2012 - pubs.rsc.org
We briefly review advances in computational actinoid (An) chemistry during the past ten
years in regard to two issues: the geometrical and electronic structures, and reactions. The …
years in regard to two issues: the geometrical and electronic structures, and reactions. The …
Molecular actinide compounds with soft chalcogen ligands
M Ephritikhine - Coordination Chemistry Reviews, 2016 - Elsevier
Molecular actinide compounds with soft chalcogen ligands - ScienceDirect Skip to main
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Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR2)2]3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H)
AJ Gaunt, SD Reilly, AE Enriquez, BL Scott… - Inorganic …, 2008 - ACS Publications
Treatment of M [N (SiMe3) 2] 3 (M= U, Pu (An); La, Ce (Ln)) with NH (EPPh2) 2 and NH (EP i
Pr2) 2 (E= S, Se), afforded the neutral complexes M [N (EPR2) 2] 3 (R= Ph, i Pr). Tellurium …
Pr2) 2 (E= S, Se), afforded the neutral complexes M [N (EPR2) 2] 3 (R= Ph, i Pr). Tellurium …
Recent advances in organoactinide chemistry as exemplified by cyclopentadienyl compounds
M Ephritikhine - Organometallics, 2013 - ACS Publications
The ubiquity of the cyclopentadienyl ligand permits us to use its complexes as
representative examples for the description of recent highlights in organometallic and more …
representative examples for the description of recent highlights in organometallic and more …
The vitality of uranium molecular chemistry at the dawn of the XXIst century
M Ephritikhine - Dalton Transactions, 2006 - pubs.rsc.org
The intent of this Dalton Perspective is to highlight the recent advances in uranium
molecular chemistry, with the results reported during the 2000–2006 period. This discipline …
molecular chemistry, with the results reported during the 2000–2006 period. This discipline …
Actinide‐Mediated Catalytic Addition of E H Bonds (E= N, P, S) to Carbodiimides, Isocyanates, and Isothiocyanates
Unprecedented catalytic reactivity of actinide coordination complexes toward
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …
Tailoring the selectivity of phenanthroline derivatives for the partitioning of trivalent Am/Eu ions–a relativistic DFT study
C Ebenezer, RV Solomon - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
In the past few years, phenanthroline-based ligands have become an attractive target for the
partitioning of trivalent actinides (Ac) from lanthanides (Ln) in nuclear waste management …
partitioning of trivalent actinides (Ac) from lanthanides (Ln) in nuclear waste management …
Does the length of the alkyl chain affect the complexation and selectivity of phenanthroline-derived phosphonate ligands?–Answers from DFT calculations
C Ebenezer, RV Solomon - Polyhedron, 2021 - Elsevier
The soft–hard-donor-combined phosphonate-based ligands are one of the popular
extractants for the separation of actinide from lanthanide in nuclear waste management …
extractants for the separation of actinide from lanthanide in nuclear waste management …
U(SMes*)n, (n = 3, 4) and Ln(SMes*)3 (Ln = La, Ce, Pr, Nd): Lanthanide(III)/Actinide(III) Differentiation in Agostic Interactions and an Unprecedented η3 Ligation …
M Roger, N Barros, T Arliguie, P Thuéry… - Journal of the …, 2006 - ACS Publications
Reaction of U (NEt2) 4 with HS-2, 4, 6-tBu3C6H2 (HSMes*) gave U (SMes*) 3 (NEt2)(py)(1),
whereas similar treatment of U [N (SiMe3) SiMe2CH2][N (SiMe3) 2] 2 afforded U (SMes*)[N …
whereas similar treatment of U [N (SiMe3) SiMe2CH2][N (SiMe3) 2] 2 afforded U (SMes*)[N …
Uranium going the soft way: low-valent uranium (III) coordinated to an arene-anchored tris-thiophenolate ligand
D Pividori, ME Miehlich, B Kestel… - Inorganic …, 2021 - ACS Publications
The synthesis of a tripodal, S-based ligand, namely the mesitylene-anchored, tris-
thiophenolate-functionalized (mes (Me, AdArS) 3) 3–(1) 3–, and its coordination chemistry …
thiophenolate-functionalized (mes (Me, AdArS) 3) 3–(1) 3–, and its coordination chemistry …