Sulfonate N‐Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C− C, C− B, C− H, and C− Si Bonds
A copper‐based complex that contains a sulfonate N‐heterocyclic carbene ligand was first
reported 15 years ago. Since then, these organometallic entities have proven to be uniquely …
reported 15 years ago. Since then, these organometallic entities have proven to be uniquely …
Development of earth-abundant metals-catalyzed enantioselective alkenylations using alkenyl metal reagents
W Liang, W Hanlin, S Jiefeng, C Jianzhong… - Acta Chimica …, 2021 - sioc-journal.cn
Allylic chiral centers are widely present in natural products and pharmaceutically active
molecules, and play a vital role in the construction of organic compounds through pericyclic …
molecules, and play a vital role in the construction of organic compounds through pericyclic …
Stereoselective Formal Hydroamidation of Si-Substituted Arylacetylenes with DIBAL-H and Isocyanates: Synthesis of (E)- and (Z)-α-Silyl-α,β-unsaturated Amides
H Lee, S Cho, Y Lee, B Jung - The Journal of Organic Chemistry, 2020 - ACS Publications
An efficient and stereoselective method for the synthesis of (E)-and (Z)-α-silyl-α, β-
unsaturated amides and its synthetic applications are presented herein. The solvent …
unsaturated amides and its synthetic applications are presented herein. The solvent …
丰产金属催化烯基金属试剂的不对称烯基化反应研究进展
吴良， 魏瀚林， 申杰峰， 陈建中， 张万斌 - 化学学报, 2021 - sioc-journal.cn
摘要烯丙位手性中心不仅广泛存在于天然产物和药物活性分子中, 也是有机合成中的重要合成砌
块. 过渡金属催化烯基金属试剂作为亲核试剂的不对称加成或偶联反应是构建这一结构非常有 …
块. 过渡金属催化烯基金属试剂作为亲核试剂的不对称加成或偶联反应是构建这一结构非常有 …
Chiral N-Heterocyclic Carbene-Based Ligands
V César, C Fliedel, A Labande - Chiral Ligands, 2021 - taylorfrancis.com
This chapter aims to provide an overview of the most successful families of chiral N-
heterocyclic carbene (NHC) ligands used in asymmetric catalysis since 2011. Over the past …
heterocyclic carbene (NHC) ligands used in asymmetric catalysis since 2011. Over the past …