Catalytic cross-coupling reactions have had a profound impact on the synthesis of
pharmaceuticals, biologically active natural products, and materials. 1 Such reactions …

I am highly honored to be the co-recipient of the Tetrahedron Prize for 2014 with Professor
Jiro Tsuji for our work on metal catalyzed allylic alkylation, notably that using palladium. In …

Das zentrale Thema der Organischen Chemie ist die Knüpfung von Kohlenstoff-Kohlenstoff-
Bindungen-Schlüsselschritte im Aufbau komplexer Moleküle aus einfachen Vorstufen. In der …

RXM+ R2X— RXR2+ MX(1) simplicity and significance, however, its synthetic utility had
been severely limited until the mid-1960s due mainly to (a) the inability ofGrignard reagents …

A guide to making optimal use of one of the most important tools available to today's
synthetic organic chemist Compatible with virtually all functional groups without protection …

In the past several years, applications of transition metal complexes in tuning the reactivity of
organocatalyst‐promoted transformations have attracted increasing attention in the synthetic …

Palladium-catalyzed decarboxylative asymmetric allylic alkylation (DAAA) of allyl enol
carbonates as a highly chemo-, regio-, and enantioselective process for the synthesis of …

Direct Catalytic Intermolecular α-Allylic Alkylation of Aldehydes by Combination of Transition-Metal
and Organocatalysis Organic Chemistry Portal Abstracts Search: Direct Catalytic Intermolecular …

Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This
book discusses the significant advances that have been made with regard to the …

We have reported in 1965 that n-allylpalfadium chloride (1) reacts with C-nucleophiles such
as malonates, acetoacetates, and enamines (Eq. l), and shown that the reaction offers a new …