Nonaqueous polar solvents in reverse micelle systems

NM Correa, JJ Silber, RE Riter, NE Levinger - Chemical Reviews, 2012 - ACS Publications
2. BACKGROUND 2.1. Aqueous Reverse Micelles The unique properties of water including
its polarity and highly structured hydrogen bond network have led to the widespread use of …

Ionic liquids in microemulsions: formulation and characterization

J Kuchlyan, N Kundu - Current Opinion in Colloid & Interface Science, 2016 - Elsevier
In the last few decades ionic liquids (ILs) have been widely considered as a “green solvents”
and they are used in various fields. ILs can be used in the formation of microemulsion as a …

A unique ionic liquid with amphiphilic properties that can form reverse micelles and spontaneous unilamellar vesicles

CC Villa, F Moyano, MR Ceolin, JJ Silber, RD Falcone… - 2012 - ri.conicet.gov.ar
Catanionic surfactants: The synthesis of a new surfactant ionic liquid with unique properties
is described. The formation of reverse micelles in benzene and large unilamellar vesicles …

Solvent Blends Can Control Cationic Reversed Micellar Interdroplet Interactions. The Effect of n-Heptane:Benzene Mixture on BHDC Reversed Micellar Interfacial …

FM Agazzi, RD Falcone, JJ Silber… - The Journal of Physical …, 2011 - ACS Publications
We have investigated, for the first time, the effect of the composition of the nonpolar organic
media on the benzyl-n-hexadecyl-dimethylammonium chloride (BHDC) reversed micelles …

How the cation 1-butyl-3-methylimidazolium impacts the interaction between the entrapped water and the reverse micelle interface created with an ionic liquid-like …

CMO Lépori, NM Correa, JJ Silber, RD Falcone - Soft Matter, 2016 - pubs.rsc.org
The behavior of the interfacial water entrapped in reverse micelles (RMs) formed by the ionic
liquid-like surfactant 1-butyl-3-methylimidazolium 1, 4-bis-2-ethylhexylsulfosuccinate (bmim …

Enzymatic Hydrolysis of N-Benzoyl-l-Tyrosine p-Nitroanilide by α-Chymotrypsin in DMSO-Water/AOT/n-Heptane Reverse Micelles. A Unique Interfacial Effect on …

F Moyano, E Setien, JJ Silber, NM Correa - Langmuir, 2013 - ACS Publications
The reverse micelle (RM) media are very good as nanoreactors because they can create a
unique microenvironment for carrying out a variety of chemical and biochemical reactions …

The effect of different interfaces and confinement on the structure of the ionic liquid 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide entrapped in …

DD Ferreyra, NM Correa, JJ Silber… - Physical Chemistry …, 2012 - pubs.rsc.org
The behavior of the ionic liquid (IL) 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl)
imide ([bmim][Tf2N]) entrapped in two reverse micelles (RMs) formed in an aromatic solvent …

More evidence on the control of reverse micelles sizes. Combination of different techniques as a powerful tool to monitor AOT reversed micelles properties

AM Durantini, R Darío Falcone, JJ Silber… - The Journal of …, 2013 - ACS Publications
In this work, we have investigated the behavior of 4-aminophthalimide (4-AP) in solvent
mixtures of ethyl lactate (EL)–water and EL–n-heptane and in reversed micelles (RMs) …

The role of hydrogen bonding in the preferential solvation of 5-aminoquinoline in binary solvent mixtures

S Das, PK Singha, AK Singh… - The Journal of Physical …, 2021 - ACS Publications
5-Aminoquinoline (5AQ) has been used as a fluorescent probe of preferential solvation (PS)
in binary solvent mixtures in which the nonpolar component is diethyl ether and the polar …

Reverse micelles for nanoparticle synthesis and biomolecule separation

RS Chaurasiya, HU Hebbar - Nanoscience in Food and Agriculture 4, 2017 - Springer
Reverse micelles are used for the selective separation and purification of biomolecules, and
for the synthesis of nanoparticles. Reverse micelles are nanometer-size droplets of aqueous …