Effect of Pd Coordination and Isolation on the Catalytic Reduction of O2 to H2O2 over PdAu Bimetallic Nanoparticles
The direct synthesis of hydrogen peroxide (H2+ O2→ H2O2) may enable low-cost H2O2
production and reduce environmental impacts of chemical oxidations. Here, we synthesize a …
production and reduce environmental impacts of chemical oxidations. Here, we synthesize a …
Direct synthesis of H2O2 on Pd and AuxPd1 clusters: Understanding the effects of alloying Pd with Au
Abstract Direct synthesis (H 2+ O 2→ H 2 O 2) could produce H 2 O 2 (an environmentally
benign oxidant) more cost-effectively and sustainably than anthraquinone oxidation …
benign oxidant) more cost-effectively and sustainably than anthraquinone oxidation …
Understanding hydrogen pressure control of furfural hydrogenation selectivity on a Pd (1 1 1) model catalyst
R Bavisotto, SP Roy, N Hopper, WT Tysoe - Journal of Catalysis, 2023 - Elsevier
We investigate the postulate that hydrogen pressure influences the furfural hydrogenation
selectivity on palladium to form decarbonylation products at low hydrogen pressures, but 2 …
selectivity on palladium to form decarbonylation products at low hydrogen pressures, but 2 …
Simulating segregation in a ternary Cu–Pd–Au alloy with density functional theory, machine learning, and Monte Carlo simulations
Simulation of the segregation profile of multicomponent alloys is important to investigate the
catalytic properties of alloy catalysts. Density functional theory (DFT) is too expensive to use …
catalytic properties of alloy catalysts. Density functional theory (DFT) is too expensive to use …
Ce 0.6 Zr 0.3 Y 0.1 O 2 nanorod supported gold and palladium alloy nanoparticles: high-performance catalysts for toluene oxidation
W Tan, J Deng, S Xie, H Yang, Y Jiang, G Guo, H Dai - Nanoscale, 2015 - pubs.rsc.org
The Ce0. 6Zr0. 3Y0. 1O2 (CZY) nanorods and their supported gold and palladium alloy
(zAuxPdy/CZY; z= 0.80–0.93 wt%; x or y= 0, 1, 2) nanoparticles (NPs) were prepared using …
(zAuxPdy/CZY; z= 0.80–0.93 wt%; x or y= 0, 1, 2) nanoparticles (NPs) were prepared using …
Promotional Role of Acid Sites on Aluminosilicate-Supported PdAu for Vinyl Acetate Synthesis
PdAu catalysts supported on both pure silica and aluminosilicates and promoted with KOAc
are the most active and selective compositions for the industrial-scale acetoxylation of …
are the most active and selective compositions for the industrial-scale acetoxylation of …
Molecular insights into the vinyl acetate synthesis on Pd/Au (1 1 1) Surface: Effects of potassium ion
H Sun, P Qiu, Y Yang, J Liu, L Zhang, Z Liu - Applied Surface Science, 2022 - Elsevier
The surface structure of bimetallic Pd/Au catalyst, accompanied by the presence of
potassium acetate (KOAc) are critical for synthesis of vinyl acetate (VAc). In this study …
potassium acetate (KOAc) are critical for synthesis of vinyl acetate (VAc). In this study …
Impregnation of KOAc on PdAu/SiO 2 causes Pd-acetate formation and metal restructuring
Potassium-promoted, oxide-supported PdAu is catalytically active for the gas-phase
acetoxylation of ethylene to form vinyl acetate monomer (VAM), in which the potassium …
acetoxylation of ethylene to form vinyl acetate monomer (VAM), in which the potassium …
The interplay between homogeneous and heterogeneous phases of PdAu catalysts for the oxidation of alcohols
The relationship between the homogeneous and heterogeneous phases of a catalyst is
widely neglected in part due to the inherent differences between the experimental and …
widely neglected in part due to the inherent differences between the experimental and …
Reducibility Studies of Ceria, Ce0.85Zr0.15O2 (CZ) and Au/CZ Catalysts after Alkali Ion Doping: Impact on Activity in Oxidation of NO and CO
EM Iwanek, LF Liotta, S Williams, L Hu, H Ju… - Catalysts, 2022 - mdpi.com
The aim of these studies was to perform thorough research on the influence of alkali metal
ions (Li, Na, K and Cs) on the properties of nanogold catalysts supported on ceria–zirconia …
ions (Li, Na, K and Cs) on the properties of nanogold catalysts supported on ceria–zirconia …