The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress | Chemical
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Carbohydrate chemistry constitutes today a “multifaceted” discipline strongly connected with
organic, pharmaceutical, and medicinal chemistry. 1 Carbohydrates are important …

Considerable effort has been devoted in the past decades to the development of new
methods for the construction of five-membered carbocycles, since they play a fundamental …

The synthesis of complex natural products still remains as the bottleneck for the biological
evaluation of such compounds. In contrast to the biosyntheses, vinylogous aldol reactions …

Influenza, a severe viral infection of the respiratory system, is responsible for substantial
morbidity and mortality rates due to annual epidemics and unpredictable pandemics, such …

A synthesis of oseltamivir (Tamiflu) was achieved starting from D-mannitol. A unique feature
of the synthetic route is that an acyclic precursor was constructed, which was then cyclized in …

The vinylogous Mukaiyama aldol (VMA) reaction allows efficient access to larger segments
for complex natural product synthesis, primarily polyketides, through the construction of …

Readily available sugar derivatives were transformed in a few steps into valuable, more
complex products. The tandem radical scission of carbohydrates− oxidation reaction gave …

A highly stereoselective and an efficient approach for studies towards the synthesis of
thermolide‐6′ has been described. The salient features of the synthesis are the utilization …

The stereoselective α‐addition to cyclic dienol silanes has rarely been exploited, in contrast
to the well‐studied γ‐addition of conjugated butenolides. In this study, an unprecedent …