Biginelli reaction: Polymer supported catalytic approaches

RV Patil, JU Chavan, DS Dalal, VS Shinde… - ACS combinatorial …, 2019 - ACS Publications
The Biginelli product, dihydropyrimidinone (DHPM) core, and its derivatives are of immense
biological importance. There are several methods reported as modifications to the original …

Current progress in asymmetric Biginelli reaction: an update

MM Heravi, R Moradi, L Mohammadkhani, B Moradi - Molecular Diversity, 2018 - Springer
The Biginelli reaction, involving a three-component reaction of an aromatic aldehyde, urea
and ethyl acetoacetate, has emerged as an extremely useful synthetic tool to organic …

Asymmetric Biginelli reaction catalyzed by silicon, titanium and aluminum oxides

OV Fedorova, YA Titova, AY Vigorov, MS Toporova… - Catalysis Letters, 2016 - Springer
The asymmetric Biginelli reaction was investigated in the presence of N-[(2 S, 4 R)-4-
hydroxyprolyl]-(S)-1-phenylethylamine as chiral inducer and silicon, titanium or aluminum …

Highly enantioselective Biginelli reaction of aliphatic aldehydes catalyzed by chiral phosphoric acids

Y Guo, Z Gao, X Meng, G Huang, H Zhong, H Yu… - Synlett, 2017 - thieme-connect.com
Several chiral phosphoric acids were evaluated as organocatalysts for the enantioselective
Biginelli reaction of aliphatic aldehydes. With a chiral phosphoric acid derived from 3, 3 …

Mixed oxides of silicon, titanium, zirconium, modified with carboxylic acids, as heterogeneous catalysts for the asymmetric Biginelli reaction

AN Murashkevich, OV Fedorova, TF Kuznetsova… - Journal of Sol-Gel …, 2023 - Springer
Using the sol-gel and coprecipitation methods, individual oxides of silicon, titanium,
zirconium and double oxides TiO2–SiO2, TiO2–ZrO2, ZrO2–SiO2 have been synthesized …

The Study of the Influence of ZrO2 Precursor Type and the Temperature of Annealing on the Crystallization of the Tetragonal Polymorph of ZrO2 in Zirconia-Silica …

A Adamczyk - Gels, 2022 - mdpi.com
Materials of the ZrO2-SiO2 system were obtained by the sol-gel method applying two
different types of ZrO2 precursors: zirconium (IV) n-propoxide Zr (OC3H7) 4 and zirconium …

New chiral proline-based catalysts for silicon and zirconium oxides-promoted asymmetric Biginelli reaction

YA Titova, DA Gruzdev, OV Fedorova… - Chemistry of …, 2018 - Springer
4-Hydroxy-(2 S)-prolines bearing 3, 4-dihydro-2 H-1, 4-benzoxazine or 1, 2, 3, 4-
tetrahydroquinoline fragments were synthesized and studied as chiral catalysts in the …

Metal oxides and silica as efficient catalysts for the preparative organic chemistry

YA Titova, OV Fedorova, GL Rusinov… - Russian Chemical …, 2015 - iopscience.iop.org
Data on the use of metal oxides and silica as catalysts of reactions that are most in demand
in laboratory organic synthesis are summarized. The potential of oxide catalysts for …

Precision in stereochemistry: the integral role of catalytic asymmetric Biginelli reaction in crafting enantiomerically pure dihydropyrimidinones

A Bendi, AS Bhathiwal, A Tiwari, GBD Rao, M Afshari - Molecular Diversity, 2024 - Springer
One well-known multicomponent reaction that is helpful in the synthesis of
dihydropyrimidinones (DHPMs), important molecules in organic synthesis and medicinal …

Оксиды металлов и кремния-эффективные катализаторы процессов препаративной органической химии

ЮА Титова, ОВ Федорова, ГЛ Русинов, ВН Чарушин - Успехи химии, 2015 - elibrary.ru
Обобщены данные по использованию оксидов металлов и кремния в качестве
катализаторов реакций, которые наиболее востребованы в лабораторном …