Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …

Molecular nitrogen (N2) is cheap and widely available, but its unreactive nature is a
challenge when attempting to functionalize it under mild conditions with other widely …

Actinide-based catalysts have been regarded as promising candidates for N 2 fixation owing
to their unique 5f orbital with flexible oxidation states. Herein, we report for the first time the …

Biological nitrogen fixation by the nitrogenase enzymes has long been a touchstone for
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …

The forefront of research into the complexes of uranium reveals chemical transformations
that challenge and expand our view of this unique element. Certain ligands form multiple …

Since uranium has several common paramagnetic oxidation states, ie, 5f 1 U5+, 5f 2 U4+,
and 5f 3 U3+, one of the analytical methods commonly used for characterizing uranium …

This review attempts to survey the recent literature concerning the coordination chemistry
and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand …

Reduction of dinitrogen (N2) is a major challenge for chemists. Cooperation of multiple
metal centers to break the strong N2 triple bond has been identified as a crucial step in both …

The electron-rich, six-coordinate tris-aryloxide uranium (III) complex [((AdArO) 3tacn)
UIII][where (AdArOH) 3tacn= 1, 4, 7-tris (3-adamantyl-5-tert-butyl-2-hydroxybenzyl) 1, 4, 7 …