Site-selective arylation of carboxamides from unprotected peptides

W Li, Y Chen, Y Chen, S Xia, W Chang… - Journal of the …, 2023 - ACS Publications
The amidated peptides are an important class of biologically active compounds due to their
unique biological properties and wide applications as potential peptide drugs and …

DFT-Enabled Development of Hemilabile (PN) Ligands for Gold(I/III) RedOx Catalysis: Application to the Thiotosylation of Aryl Iodides

K Muratov, E Zaripov, MV Berezovski… - Journal of the American …, 2024 - ACS Publications
Ligand-enabled oxidative addition of Csp2-X bonds to Au (I) centers has recently appeared
as a valuable strategy for the development of catalytic RedOx processes. Several cross …

Ligand-Enabled Gold-Catalyzed C(sp2)–O Cross-Coupling Reactions

A Das, NT Patil - ACS Catalysis, 2023 - ACS Publications
Reported herein is a ligand-enabled gold-catalyzed C (sp2)–O cross-coupling reaction of
aryl iodides and aliphatic alcohols. The synthesis of a variety of aryl alkyl ethers including …

Unlocking the Chain‐Walking Process in Gold Catalysis

VW Bhoyare, AG Tathe, V Gandon… - Angewandte Chemie …, 2023 - Wiley Online Library
The successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …

Gold–manganese bimetallic redox coupling with light

S Xia, W Li, H Chen, C Zhu, J Han… - Journal of the American …, 2023 - ACS Publications
The classical Au (I)/Au (III) redox couple chemistry has been limited to constructing C–C and
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …

Ligand‐Enabled Gold‐Catalyzed Cyanation of Organohalides

A Kumar, N Bhattacharya, MV Mane… - Angewandte Chemie …, 2024 - Wiley Online Library
Herein, we disclose the first report on gold‐catalyzed C (sp2)‐CN cross‐coupling reaction
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …

Hemilabile P, N-ligand-assisted gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes

C Wei, L Zhang, Z Xia - Organic Letters, 2023 - ACS Publications
A gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes was developed. The
hemilabile P, N-ligand-assisted gold-catalyzed C (sp2)–C (sp2) cross-coupling can …

Consolidation of the Oxidant‐Free Au (I)/Au (III) Catalysis Enabled by the Hemilabile Ligand Strategy

P Font, H Valdés, X Ribas - Angewandte Chemie, 2024 - Wiley Online Library
In this minireview we survey the challenges and strategies in gold redox catalysis. Gold's
reluctance to oxidative addition reactions due to its high redox potential limits its …

Gold-catalyzed alkenylation and arylation of phosphorothioates

S Mishra, NT Patil - Chemical Science, 2023 - pubs.rsc.org
Reported herein is the ligand-enabled gold-catalyzed alkenylation and arylation of
phosphorothioates using alkenyl and aryl iodides. Mechanistic studies revealed a crucial …

Gold‐Catalyzed 1, 2‐Dicarbofunctionalization of Alkynes with Organohalides

SP Sancheti, Y Singh, MV Mane… - Angewandte Chemie, 2023 - Wiley Online Library
Herein, we report the first gold‐catalyzed 1, 2‐dicarbofunctionalization of alkynes using
organohalides as non‐prefunctionalized coupling partners. The mechanism of the reaction …