Site-selective arylation of carboxamides from unprotected peptides
W Li, Y Chen, Y Chen, S Xia, W Chang… - Journal of the …, 2023 - ACS Publications
The amidated peptides are an important class of biologically active compounds due to their
unique biological properties and wide applications as potential peptide drugs and …
unique biological properties and wide applications as potential peptide drugs and …
DFT-Enabled Development of Hemilabile (P∧N) Ligands for Gold(I/III) RedOx Catalysis: Application to the Thiotosylation of Aryl Iodides
K Muratov, E Zaripov, MV Berezovski… - Journal of the American …, 2024 - ACS Publications
Ligand-enabled oxidative addition of Csp2-X bonds to Au (I) centers has recently appeared
as a valuable strategy for the development of catalytic RedOx processes. Several cross …
as a valuable strategy for the development of catalytic RedOx processes. Several cross …
Ligand-Enabled Gold-Catalyzed C(sp2)–O Cross-Coupling Reactions
Reported herein is a ligand-enabled gold-catalyzed C (sp2)–O cross-coupling reaction of
aryl iodides and aliphatic alcohols. The synthesis of a variety of aryl alkyl ethers including …
aryl iodides and aliphatic alcohols. The synthesis of a variety of aryl alkyl ethers including …
Unlocking the Chain‐Walking Process in Gold Catalysis
The successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …
Gold–manganese bimetallic redox coupling with light
S Xia, W Li, H Chen, C Zhu, J Han… - Journal of the American …, 2023 - ACS Publications
The classical Au (I)/Au (III) redox couple chemistry has been limited to constructing C–C and
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …
Ligand‐Enabled Gold‐Catalyzed Cyanation of Organohalides
Herein, we disclose the first report on gold‐catalyzed C (sp2)‐CN cross‐coupling reaction
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …
Hemilabile P, N-ligand-assisted gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes
C Wei, L Zhang, Z Xia - Organic Letters, 2023 - ACS Publications
A gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes was developed. The
hemilabile P, N-ligand-assisted gold-catalyzed C (sp2)–C (sp2) cross-coupling can …
hemilabile P, N-ligand-assisted gold-catalyzed C (sp2)–C (sp2) cross-coupling can …
Consolidation of the Oxidant‐Free Au (I)/Au (III) Catalysis Enabled by the Hemilabile Ligand Strategy
In this minireview we survey the challenges and strategies in gold redox catalysis. Gold's
reluctance to oxidative addition reactions due to its high redox potential limits its …
reluctance to oxidative addition reactions due to its high redox potential limits its …
Gold-catalyzed alkenylation and arylation of phosphorothioates
Reported herein is the ligand-enabled gold-catalyzed alkenylation and arylation of
phosphorothioates using alkenyl and aryl iodides. Mechanistic studies revealed a crucial …
phosphorothioates using alkenyl and aryl iodides. Mechanistic studies revealed a crucial …
Gold‐Catalyzed 1, 2‐Dicarbofunctionalization of Alkynes with Organohalides
Herein, we report the first gold‐catalyzed 1, 2‐dicarbofunctionalization of alkynes using
organohalides as non‐prefunctionalized coupling partners. The mechanism of the reaction …
organohalides as non‐prefunctionalized coupling partners. The mechanism of the reaction …