Tetrel bonding interactions at work: Impact on tin and lead coordination compounds

A Bauzá, SK Seth, A Frontera - Coordination Chemistry Reviews, 2019 - Elsevier
A tetrel bond can be defined as an interaction between any electron donating moiety and a
group 14 element acting as Lewis acid. Experimental and theoretical research on this …

An investigation into three-dimensional octahedral multi-nuclear Ni (II)-based complexes supported by a more flexible salamo-type ligand

YJ Li, SZ Guo, T Feng, KF Xie, WK Dong - Journal of Molecular Structure, 2021 - Elsevier
Two new tri-and tetra-nuclear Ni (II)-based complexes,[{NiL (EtOH)(μ-OAc)} 2 Ni]· 4EtOH (1)
and [Ni 4 L 2 (μ 3-OMe) 4 (MeOH) 4](2), supported by a more flexible salamo-type ligand H 2 …

Unravelling the synthetic mimic, spectroscopic insights, and supramolecular crystal engineering of an innovative heteronuclear Pb (II)-salen cocrystal: an integrated …

D Majumdar, JE Philip, B Tüzün, A Frontera… - Journal of Inorganic and …, 2022 - Springer
Spontaneous self-assembly in the supramolecular entity is one of the enthralling synthetic
routes. It produces disparate structure crystal complexes after selecting suitable ML …

Importance of π-interactions involving chelate rings in addition to the tetrel bonds in crystal engineering: A combined experimental and theoretical study on a series of …

S Mirdya, S Roy, S Chatterjee, A Bauzá… - Crystal Growth & …, 2019 - ACS Publications
Five heteronuclear nickel (II)/lead (II) complexes with two compartmental reduced Schiff
base ligands were prepared and characterized. Their structures were confirmed by single …

Spodium bonding and other non-covalent interactions assisted supramolecular aggregation in a new mercury (II) complex of a nicotinohydrazide derivative

G Mahmoudi, E Zangrando, B Miroslaw… - Inorganica Chimica …, 2021 - Elsevier
In this work we report a new Hg (II) coordination compound [Hg (HL)(SCN) 2], which was
readily obtained from a mixture of Hg (SCN) 2 and N'-(1-(pyridin-2-yl) ethylidene) …

Antitumor effects of novel nickel–hydrazone complexes in lung cancer cells

B Ay, O Şahin, BS Demir, Y Saygideger… - New Journal of …, 2020 - pubs.rsc.org
In this work we have synthesized and characterized two new mononuclear nickel (II)
complexes [NiLI]· CH3CN (1· CH3CN) and [Ni (H2LII)(NCS) 2]· 0.5 H2O (2· 0.5 H2O) …

On the importance of π-hole spodium bonding in tricoordinated Hg II complexes

G Mahmoudi, A Masoudiasl, MG Babashkina… - Dalton …, 2020 - pubs.rsc.org
A new coordination polymer [Hg (LI) I] n (1) and a new discrete coordination complex [Hg
(HLII) I2](2) are synthesized and X-ray characterized. The existence of positive π-holes at …

On the pivotal role of tetrel bonding in the supramolecular architectures of Pb II–NCS complexes with chelating thiosemicarbazide derivatives

B Eftekhari-Sis, I García-Santos, A Castiñeiras… - …, 2024 - pubs.rsc.org
Three new PbII complexes [Pb (LI)(SCN)] n,{[Pb (LII)](SCN)} n and {[Pb (HLIII)(SCN)](SCN)}
n (HLI= N′-phenyl (pyridin-2-yl) methylene-N-phenylthiosemicarbazide, HLII= N′-amino …

Supramolecular architecture constructed from the hemidirected lead (II) complex with N'-(4-hydroxybenzylidene) isonicotinohydrazide

FA Afkhami, G Mahmoudi, F Qu, A Gupta… - Inorganica Chimica …, 2020 - Elsevier
In this work we have directed our attention to the N'-(4-hydroxybenzylidene)
isonicotinohydrazide (HL) as a linker for the production of a Pb (II) extended structure. As a …

Lead (II) compounds with neutral coordination of semicarbazones: Synthesis and characterization

VO Araujo, GA Casagrande, B Tirloni… - Inorganica Chimica …, 2022 - Elsevier
benzoylpyridine semicarbazide/4-phenylsemicarbazide derived ligands as hydrochloride
salts,[H 2 L] Cl and [H 2 L Ph] Cl· 2H 2 O, react with Pb 2+ ions in aqueous and organic …