Mononuclear Cu–O2 Complexes: Geometries, Spectroscopic Properties, Electronic Structures, and Reactivity
Using interwoven experimental and theoretical methods, detailed studies of several
structurally defined 1: 1 Cu–O2 complexes have provided important fundamental chemical …
structurally defined 1: 1 Cu–O2 complexes have provided important fundamental chemical …
Metal binding calixarenes with potential biomimetic and biomedical applications
DT Schühle, JA Peters, J Schatz - Coordination Chemistry Reviews, 2011 - Elsevier
This article exploits the special geometry of calixarene derivatives and the resulting metal
binding properties with a focus on biomedical applications. The use of calixarenes as …
binding properties with a focus on biomedical applications. The use of calixarenes as …
Spectroscopic and computational studies of an end-on bound superoxo-Cu (II) complex: geometric and electronic factors that determine the ground state
JS Woertink, L Tian, D Maiti, HR Lucas… - Inorganic …, 2010 - ACS Publications
A variety of techniques including absorption, magnetic circular dichroism (MCD), variable-
temperature, variable-field MCD (VTVH-MCD), and resonance Raman (rR) spectroscopies …
temperature, variable-field MCD (VTVH-MCD), and resonance Raman (rR) spectroscopies …
Redox properties of a mononuclear copper (II)-superoxide complex
T Tano, Y Okubo, A Kunishita, M Kubo… - Inorganic …, 2013 - ACS Publications
Redox properties of a mononuclear copper (II) superoxide complex,(L) CuII–OO•, supported
by a tridentate ligand (L= 1-(2-phenethyl)-5-[2-(2-pyridyl) ethyl]-1, 5-diazacyclooctane) have …
by a tridentate ligand (L= 1-(2-phenethyl)-5-[2-(2-pyridyl) ethyl]-1, 5-diazacyclooctane) have …
Stereoelectronic effects on molecular geometries and state-energy splittings of ligated monocopper dioxygen complexes
The relative energies of side-on versus end-on binding of molecular oxygen to a supported
Cu (I) species, and the singlet versus triplet nature of the ground electronic state, are …
Cu (I) species, and the singlet versus triplet nature of the ground electronic state, are …
Quantum effects in biological electron transfer
Over recent decades, quantum effects such as coherent electronic energy transfers, electron
and hydrogen tunneling have been uncovered in biological processes. In this Perspective …
and hydrogen tunneling have been uncovered in biological processes. In this Perspective …
Long distance electron-transfer mechanism in peptidylglycine α-hydroxylating monooxygenase: A perfect fitting for a water bridge
The active sites of copper enzymes have been the subject of many theoretical and
experimental investigations from a number of years. Such studies have embraced topics …
experimental investigations from a number of years. Such studies have embraced topics …
Probing the Mechanism of O2 Activation by a Copper(I) Biomimetic Complex of a C−H Hydroxylating Copper Monooxygenase
In this paper, we report, for the first time, a plausible full reaction pathway for the activation of
O2 by a tetraazamacrocyclic monocopper (I) complex and for the subsequent intramolecular …
O2 by a tetraazamacrocyclic monocopper (I) complex and for the subsequent intramolecular …
Understanding Lead Chemistry from Topological Insights: The Transition between Holo‐ and Hemidirected Structures within the [Pb(CO)n]2+ Model Series
C Gourlaouen, H Gérard, JP Piquemal… - … –A European Journal, 2008 - Wiley Online Library
In this Contribution, we focus to the currently unknown [Pb (CO) n] 2+ model series (n= 1 to
10), a set of compounds which allows us to investigate in‐depth the holo‐and …
10), a set of compounds which allows us to investigate in‐depth the holo‐and …