[HTML][HTML] Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications

AJ Carrod, V Gray, K Börjesson - Energy & Environmental Science, 2022 - pubs.rsc.org
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …

Molecular Control of Triplet-Pair Spin Polarization and Its Optoelectronic Magnetic Resonance Probes

OG Reid, JC Johnson, JD Eaves… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Preparing and manipulating pure magnetic states in molecular systems are the
key initial requirements for harnessing the power of synthetic chemistry to drive practical …

Spin statistics for triplet–triplet annihilation upconversion: Exchange coupling, intermolecular orientation, and reverse intersystem crossing

DG Bossanyi, Y Sasaki, S Wang, D Chekulaev… - JACS Au, 2021 - ACS Publications
Triplet–triplet annihilation upconversion (TTA-UC) has great potential to significantly
improve the light harvesting capabilities of photovoltaic cells and is also sought after for …

Controlling Intramolecular Singlet Fission Dynamics via Torsional Modulation of Through-Bond versus Through-Space Couplings

K Majumder, S Mukherjee, NA Panjwani… - Journal of the …, 2023 - ACS Publications
Covalent dimers, particularly pentacenes, are the dominant platform for developing a
mechanistic understanding of intramolecular singlet fission (iSF). Numerous studies have …

[HTML][HTML] In optimized rubrene-based nanoparticle blends for photon upconversion, singlet energy collection outcompetes triplet-pair separation, not singlet fission

DG Bossanyi, Y Sasaki, S Wang… - Journal of Materials …, 2022 - pubs.rsc.org
The conversion of near-infrared photons to visible light through triplet–triplet annihilation
upconversion offers an enticing strategy for significantly boosting the efficiency of …

A molecular perspective on quantum information

GD Scholes - Proceedings of the Royal Society A, 2023 - royalsocietypublishing.org
Some of the fundamentals of quantum information science are described, including the
concepts of quantum resources, quantum states and mixedness of states. The explanations …

[HTML][HTML] Steering the multiexciton generation in slip-stacked perylene dye array via exciton coupling

Y Hong, M Rudolf, M Kim, J Kim, T Schembri… - Nature …, 2022 - nature.com
Dye arrays from dimers up to larger oligomers constitute the functional units of natural light
harvesting systems as well as organic photonic and photovoltaic materials. Whilst in the past …

[HTML][HTML] Parallel triplet formation pathways in a singlet fission material

N Maity, W Kim, NA Panjwani, A Kundu… - Nature …, 2022 - nature.com
Harvesting long-lived free triplets in high yields by utilizing organic singlet fission materials
can be the cornerstone for increasing photovoltaic efficiencies potentially. However, except …

What next for singlet fission in photovoltaics? The fate of triplet and triplet-pair excitons

RJ Hudson, AN Stuart, DM Huang… - The Journal of Physical …, 2022 - ACS Publications
Exciton multiplication through singlet fission (SF) has the potential to surpass the detailed-
balance efficiency limit of single-junction photovoltaic (PV) devices. However, energy loss …

Tetracene Dimers: A Platform for Intramolecular Down-and Up-conversion

Y Bo, Y Hou, D Thiel, R Weiß, T Clark… - Journal of the …, 2023 - ACS Publications
Photon energy conversion can be accomplished in many different ways, including the two
opposing manners, down-conversion (ie, singlet fission, SF) and up-conversion (ie, triplet …