Exploring the Structural, Dynamic, and Functional Properties of Metal‐Organic Frameworks through Molecular Modeling

F Formalik, K Shi, F Joodaki, X Wang… - Advanced Functional …, 2024 - Wiley Online Library
This review spotlights the role of atomic‐level modeling in research on metal‐organic
frameworks (MOFs), especially the key methodologies of density functional theory (DFT) …

A comprehensive review on the use of metal–organic frameworks (MOFs) coupled with enzymes as biosensors

JES Souza, GP Oliveira, JYNH Alexandre, JGL Neto… - Electrochem, 2022 - mdpi.com
Several studies have shown the development of electrochemical biosensors based on
enzymes immobilized in metal–organic frameworks (MOFs). Although enzymes have unique …

Theoretical isotherm equation for adsorption-induced structural transition on flexible metal–organic frameworks

S Hiraide, Y Sakanaka, Y Iida… - Proceedings of the …, 2023 - National Acad Sciences
Flexible metal–organic frameworks (MOFs) exhibit an adsorption-induced structural
transition known as “gate opening” or “breathing,” resulting in an S-shaped adsorption …

Tröger's base network polymers of intrinsic microporosity (TB-PIMs) with tunable pore size for heterogeneous catalysis

AR Antonangelo, N Hawkins, E Tocci… - Journal of the …, 2022 - ACS Publications
Heterogeneous catalysis plays a pivotal role in the preparation of value-added chemicals,
and it works more efficiently when combined with porous materials and supports. Because of …

Spatiotemporal Design of the Metal–Organic Framework DUT‐8 (M)

H Miura, V Bon, I Senkovska, S Ehrling… - Advanced …, 2023 - Wiley Online Library
Switchable metal–organic frameworks (MOFs) change their structure in time and selectively
open their pores adsorbing guest molecules, leading to highly selective separation …

Tuning microscopic structure of Al-based metal-organic frameworks by changing organic linkers for efficient phosphorus removal

S Li, Q Zhang, C Yin, J Chen, X Yang… - Journal of Cleaner …, 2021 - Elsevier
In this study, five aluminum-based metal-organic frameworks (ie Al-BDC, Al-BDC-NH 2, Al-
BHTA, Al-PMA and Al-BPDC) were synthesized by changing the organic linker. Among the …

Nano-porous bimetallic organic frameworks (Fe/Co)-BDC, a breathing MOF for rapid and capacitive removal of Cr-oxyanions from water

O Abuzalat, H Tantawy, M Mokhtar, A Baraka - Journal of Water Process …, 2022 - Elsevier
The bimetallic organic framework (MOF), MIL-53 type,(Fe/Co)-BDC was facilely synthesized
solvo-thermally at 100° C.(Fe/Co)-BDC. The as-synthesized (Fe/Co)-BDC was characterized …

Inlaying metal-organic framework derived pancake-like TiO2 into three-dimensional BiOI for visible-light-driven generation of vanillin from sodium lignosulfonate

J Qiu, D Dai, L Zhang, Y Zhou, L Yang, J Yao - Journal of Colloid and …, 2022 - Elsevier
Abstract Pancake-like TiO 2 (M-TiO 2) derived from the metal-organic framework was inlaid
into three-dimensional flower-like BiOI through a facile solvothermal method. M-TiO 2 …

A highly stable terbium (III) metal-organic framework MOF-76 (Tb) for hydrogen storage and humidity sensing

A Garg, M Almáši, R Saini, DR Paul, A Sharma… - … Science and Pollution …, 2023 - Springer
The present study described the synthesis and characterization of MOF-76 (Tb) for hydrogen
storage and humidity sensing applications. The structure and morphology of as-synthesized …

Theoretical and Experimental Insights into the Spatial Distribution of Functional Groups in a Multivariate Flexible Metal–Organic Framework

K Roztocki, MK Dudek, M Szufla, F Formalik… - Chemistry of …, 2024 - ACS Publications
Dynamic multicomponent metal–organic frameworks, comprising numerous functional
groups attached to a flexible backbone, expedite the complexity of coordination chemistry …