The activation and utilization of substrates mediated by Frustrated Lewis Pairs (FLPs) was
initially believed to occur solely via a two-electron, cooperative mechanism. More recently …

Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Single electron transition reactions between amines (Lewis base) and B (C6F5) 3 (Lewis
acid) in cooperation with benzoquinones gave rise to a frustrated radical pair 3 and a …

This work describes a strategy not only to isolate a dynamically stable radical with physical
property tunability, but to efficiently regulate the radical dissociation with reversibility and …

Strong molecular dopants for organic semiconductors that are stable against diffusion are in
demand, enhancing the performance of organic optoelectronic devices. The conventionally …

We report herein a convenient one-pot synthesis for the shelf-stable molecular complex [Mn
(NO3) 3 (OPPh3) 2](2) and describe the properties that make it a powerful and selective one …

This work describes a Lewis-acid-coordination strategy to efficiently enhance the
electrophilicity of a carbene beyond structural modification. A hybrid BCF–DAC is formed by …

Advances in the field of frustrated Lewis pair (FLP) chemistry have led to the discovery of
radical pairs, obtained by a single-electron transfer (SET) from the Lewis base to the Lewis …

Chemical doping of organic semiconductors is an essential enabler for applications in
electronic and energy-conversion devices such as thermoelectrics. Here, Lewis-paired …

First examples of diborane (6) dianions decorated with weakly coordination B (C6F5) 3
(BCF) groups and SiEt3+ moieties have been synthesized demonstrating the synthetic …