“Non‐VSEPR” Structures and Bonding in d0 Systems

M Kaupp - Angewandte Chemie International Edition, 2001 - Wiley Online Library
Under certain circumstances, metal complexes with a formal d0 electronic configuration may
exhibit structures that violate the traditional structure models, such as the VSEPR concept or …

Volatile metal alkoxides according to the concept of donor functionalization

WA Herrmann, NW Huber… - … International Edition in …, 1995 - Wiley Online Library
Since the fundamental works of DC Bradley and RC Mehrotra, metal alkoxides have
attracted attention because of the diversity of their low‐and high‐molecular‐weight …

Solvent control in the synthesis of 3, 6-bis (pyridin-3-yl)-1, 2, 4, 5-tetrazine-bridged cadmium (II) and zinc (II) coordination polymers

MA Withersby, AJ Blake, NR Champness… - Inorganic …, 1999 - ACS Publications
The reaction of cadmium (II) and zinc (II) salts with 3, 6-bis (pyridin-3-yl)-1, 2, 4, 5-tetrazine
(3, 3 '-pytz) affords coordination polymers, the structures of which are controlled by the …

Dimethylcalcium

BM Wolf, C Stuhl, C Maichle-Mössmer… - Journal of the …, 2018 - ACS Publications
The salt metathesis reaction between homoleptic calcium bis (trimethylsilyl) amide [Ca {N
(SiMe3) 2} 2] 2 and “halide-free” methyllithium allowed for the isolation of X-ray-amorphous …

Synthesis, properties, and reactivity of alkaline earth metal bis [bis (trialkylsilyl) amides]

M Westerhausen - Coordination chemistry reviews, 1998 - Elsevier
Due to their reactivity, the alkaline earth metal bis [bis (trimethylsilyl) amides] are valuable
synthons to incorporate the metal atoms in numerous molecules. The easy access of these …

A review of Group 2 (Ca, Sr, Ba) metal-organic compounds as precursors for chemical vapor deposition

WA Wojtczak, PF Fleig, MJ Hampden-Smith - Advances in Organometallic …, 1996 - Elsevier
There is considerable interest in the deposition of films containing the Group 2 elements
because these films exhibit a variety of technologically important properties. These materials …

Effect of Included Solvent Molecules on the Physical Properties of the Paramagnetic Charge Transfer Salts β' '-(bedt-ttf)4[(H3O)Fe(C2O4)3]·Solvent (bedt-ttf = Bis …

SS Turner, P Day, KMA Malik, MB Hursthouse… - Inorganic …, 1999 - ACS Publications
The new charge transfer salt, β ''-(bedt-ttf) 4 [(H3O) Fe (C2O4) 3]⊙ C5H5N, I,(bedt-ttf= bis
(ethylenedithio) tetrathiafulvalene) has a crystal structure closely similar to that of the …

NMR-spektroskopische und strukturelle charakterisierung der tri-iso-propylsilylphosphanide des calciums

M Westerhausen, R Löw, W Schwarz - Journal of organometallic chemistry, 1996 - Elsevier
The reaction of (1, 2-dimethoxyethane-O, O′) lithium phosphanide with chloro tri-iso-
propylsilane yields tri-iso-propylsilylphosphane 1 as well as bis (tri-iso-propylsilyl) …

Asymmetric epoxidation of enones employing polymeric α-amino acids in non-aqueous media

PA Bentley, S Bergeron, MW Cappi, DE Hibbs… - Chemical …, 1997 - pubs.rsc.org
Asymmetric epoxidation of enones employing polymeric a-amino acids in non-aqueous media
Page 1 O R2 R1 O C H H R1 O R2 1a–d Poly(amino acid)s 2a–d a R1 = R2 = Ph b R1 …

Dinuclear iron carbonyl complexes with dithiolate ligands: X-ray structures of [Fe2 (CO) 6 {μ-SCCHCHC (CH3) CHCS}] and [Fe2 (CO) 5 {μ-SCCHCHC (CH3) CHCS} …

MM Hasan, MB Hursthouse, SE Kabir, KMA Malik - Polyhedron, 2001 - Elsevier
The reactions of Na2 [Fe (CO) 4] with 3, 4-toluenedithiol and 1, 3-propanedithiol at room
temperature give the dinuclear complexes [Fe2 (CO) 6 {μ-SCCHCHC (CH 3) CHC S}](1) and …