Carbophilic activation of π-systems via gold coordination: Towards regioselective access of intermolecular addition products
C Praveen - Coordination Chemistry Reviews, 2019 - Elsevier
The utilization of intermolecular addition of carbon–carbon π-bonded systems as atom-
economical approach is a topic of significant interest in synthetic organic chemistry. Apart …
economical approach is a topic of significant interest in synthetic organic chemistry. Apart …
Homogeneous Gold Catalysis for Regioselective Carbocyclization of Alkynyl Precursors
C Praveen, S Szafert - ChemPlusChem, 2023 - Wiley Online Library
Abstract π‐Activation of alkynyl precursors possessing an endogenous carbon nucleophile
is one of the imperative topics in homogeneous gold catalysis as it offers Csp3‐Csp2 and …
is one of the imperative topics in homogeneous gold catalysis as it offers Csp3‐Csp2 and …
Harnessing the TEMPO-catalyzed aerobic oxidation for Machetti–De Sarlo reaction toward sustainable synthesis of isoxazole libraries
M Vadivelu, S Sampath, K Muthu… - The Journal of …, 2019 - ACS Publications
A practical synthesis of isoxazole/isoxazoline derivatives via Machetti–De Sarlo reaction
under sustainable conditions has been accomplished. This protocol involves the use of …
under sustainable conditions has been accomplished. This protocol involves the use of …
Ultrasound-assisted catalyst free synthesis of 1, 4-/1, 5-disubstituted-1, 2, 3-triazoles in aqueous medium
T Kiranmye, M Vadivelu, S Sampath, K Muthu… - Sustainable Chemistry …, 2021 - Elsevier
A convenient and straight forward strategy for the synthesis of 1-substituted-4-acyl-1, 2, 3-
triazoles and 1, 5-disubstituted-1, 2, 3-triazoles via eliminative [3+ 2] cycloaddition of azides …
triazoles and 1, 5-disubstituted-1, 2, 3-triazoles via eliminative [3+ 2] cycloaddition of azides …
Cycloisomerization of π‐Coupled Heteroatom Nucleophiles by Gold Catalysis: En Route to Regiochemically Defined Heterocycles
C Praveen - 2021 - Wiley Online Library
Since the dawn of millennium, catalytic gold chemistry is at the forefront to set off diverse
organic reactions via unique activation of π‐bonded molecules. Within this purview …
organic reactions via unique activation of π‐bonded molecules. Within this purview …
Mechanosynthesis of Triazolyl‐bis(indolyl)methane Pharmacophores via Gold Catalysis: A Prelude to Their Molecular Electronic Properties and Biological Potency
R Sundaramoorthy, M Vadivelu, K Karthikeyan… - …, 2023 - Wiley Online Library
Abstract Chemical structures possessing both 1, 2, 3‐triazole and bis (indolyl) methane
fragments gained considerable interest in drug synthesis owing to their established …
fragments gained considerable interest in drug synthesis owing to their established …
2-Amino-4, 5-dihydrothiophene-3-carbonitriles: A New Synthesis, Quantum Chemical Studies, and Mannich-Type Reactions Leading to New Hexahydrothieno [2, 3-d] …
VV Dotsenko, AV Bespalov, AS Vashurin… - ACS …, 2021 - ACS Publications
trans-2-Amino-4-aryl-5-benzoyl-4, 5-dihydrothiophene-3-carbonitriles were prepared either
by the reaction of 3-aryl-2-cyanothioacrylamides with α-thiocyanatoacetophenone or by the …
by the reaction of 3-aryl-2-cyanothioacrylamides with α-thiocyanatoacetophenone or by the …
Fine-tuning the optoelectronic chattels of fluoreno-thiophene centred molecular semiconductors through symmetric and asymmetric push–pull switch
C Kumar, AA Raheem, K Pandian… - New Journal of …, 2019 - pubs.rsc.org
Three new π-conjugated semiconductors of the type D–π–D, A–π–A (symmetric), and D–π–
A (asymmetric) were constructed on fluoreno-thiophene spacer by permutation of the lateral …
A (asymmetric) were constructed on fluoreno-thiophene spacer by permutation of the lateral …
Mechanochemistry Enabled Construction of Isoxazole Skeleton via CuO Nanoparticles Catalyzed Intermolecular Dehydrohalogenative Annulation
M Vadivelu, S Sampath, K Muthu… - Advanced Synthesis …, 2021 - Wiley Online Library
A dehydrohalogenative approach for isoxazole annulation by partnering β‐vinyl halides and
α‐nitrocarbonyls under mechanochemical setting was accomplished. This chemistry is …
α‐nitrocarbonyls under mechanochemical setting was accomplished. This chemistry is …
Sunlight‐Assisted Photocatalytic Sustainable Synthesis of 1,4‐Disubstituted 1,2,3‐Triazoles and Benzimidazoles Using TiO2−Cu2(OH)PO4 Under Solvent‐Free …
T Kiranmye, M Vadivelu, D Magadevan… - …, 2021 - Wiley Online Library
Herein, we report the facile synthesis of 1, 4‐disubstituted 1, 2, 3‐triazoles and
benzimidazoles using TiO2− Cu2 (OH) PO4 as an efficient sunlight active nanophotocatalyst …
benzimidazoles using TiO2− Cu2 (OH) PO4 as an efficient sunlight active nanophotocatalyst …