Uncatalyzed transfer hydrogenation and transfer hydrogenolysis: two novel types of hydrogen‐transfer reactions

C Rüchardt, M Gerst, J Ebenhoch - … Chemie International Edition …, 1997 - Wiley Online Library
Uncatalyzed transfer hydrogenations are H2‐transfer reactions in which donors that contain
weakly bound hydrogen atoms undergo an H‐atom transfer (retrodisproportionation) onto …

Investigation of the mechanism of the intramolecular Scholl reaction of contiguous phenylbenzenes

P Rempala, J Kroulík, BT King - The Journal of Organic Chemistry, 2006 - ACS Publications
Two mechanisms of the Scholl reaction were investigated in the series 1, 2,..., n-
oligophenylbenzenes (n= 2, 3, 4, 6) at the B3LYP/6-31G (d) level of theory. A mechanism …

Enantioselective Synthesis of Triarylmethanes via Intermolecular C–H Functionalization of Cyclohexadienes with Diaryldiazomethanes

M Lee, HML Davies - Organic Letters, 2023 - ACS Publications
Rhodium-catalyzed C–H functionalization of cyclohexadiene derivatives with
diaryldiazomethanes followed by oxidation with DDQ provides ready access to …

A review on electronic spectral studies of charge transfer complexes

UM Rabie - Journal of Molecular Structure, 2013 - Elsevier
The electronic absorption spectra of several charge transfer (CT) interactions have showed
appearance and/or disappearance of spectral bands in correlation with the lapse of time …

Mechanisms of hydride abstractions by Quinones

X Guo, H Zipse, H Mayr - Journal of the American Chemical …, 2014 - ACS Publications
The kinetics of the hydride abstractions by 2, 3-dichloro-5, 6-dicyano-p-benzoquinone
(DDQ) from 13 C–H hydride donors (acyclic 1, 4-dienes, cyclohexa-1, 4-dienes …

Intermolecular cyclopropanation versus CH insertion in RhII-catalyzed carbenoid reactions

P Müller, S Tohill - Tetrahedron, 2000 - Elsevier
The product ratio of intermolecular insertion and cyclopropanation in transition metal-
catalyzed diazo decompositions depends strongly upon the metal, its ligands and upon the …

Reactions of carbocations with unsaturated hydrocarbons: Electrophilic alkylation or hydride abstraction?

H Mayr, G Lang, AR Ofial - Journal of the American Chemical …, 2002 - ACS Publications
Benzhydryl cations were used as reference electrophiles to determine the hydride donor
reactivities of unsaturated hydrocarbons. The kinetics of the reactions were followed by UV …

Organophotocatalytic Reduction of Benzenes to Cyclohexenes

K Devi, A Shehzad, MP Wiesenfeldt - Journal of the American …, 2024 - ACS Publications
The reduction of abundant benzene rings to scarce C (sp3)-rich motifs is invaluable for drug
design, as C (sp3) content is known to correlate with clinical success. Cyclohexenes are …

From Central to Helical Chirality: Synthesis of P and M Enantiomers of [5]Helicenequinones and Bisquinones from (SS)‐2‐(p‐Tolylsulfinyl)‐ 1,4‐benzoquinone

MC Carreño, S García‐Cerrada… - Chemistry–A European …, 2003 - Wiley Online Library
Abstract The reaction of 1, 4‐divinyl‐1, 3‐cyclohexadiene, 5, 8‐dimethoxy‐or tert‐
butyldimethylsilyloxy‐3‐vinyl‐1, 2‐dihydrophenanthrene or 6‐vinyl‐7, 8‐dihydro‐1, 4 …

Facile synthesis of 2H-indazole derivatives starting from the Baylis–Hillman adducts of 2-cyclohexen-1-one

KY Lee, S Gowrisankar, JN Kim - Tetrahedron letters, 2005 - Elsevier
Facile synthesis of 2H-indazole derivatives starting from the Baylis–Hillman adducts of 2-cyclohexen-1-one
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