This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

DFT calculations form the basis of a model capable of predicting the air stability of
phosphines. The sensitivity of 18 primary phosphines is accounted for; the model also …

Fluorogenic dyes such as FlAsH and ReAsH are used widely to localize, monitor, and
characterize proteins and their assemblies in live cells. These bis-arsenical dyes can …

14b. By contrast, treatment of (R)-2 and (S)-3 with base to generate the phosphides,
followed by the addition of a chiral cyclic sulfate gave the hybrid MOP phospholanes (R, R …

Primary phosphines are renowned for being toxic, volatile, pyrophoric compounds which
have to be handled under an inert atmosphere due to their ease of air-oxidation. Thus …

The strength of conjugation between the lone pair on phosphorus atom and aryl, alkenyl and
styryl moieties of several phosphines has been quantitatively characterized by the use of …

The microwave spectrum of (2-chloroethyl) amine, ClCH2CH2NH2, has been investigated in
the 22− 120 GHz region. Five rotameric forms are possible for this compound. In two of these …

The gas-phase molecular structure of iso-propyl (tert-butyl)(trichlorosilyl) phosphine has
been determined using a combination of gas electron diffraction and computational …

Abstract Azido (difluoro) phosphane, F2PN3, is a colorless gas, which freezes to a glassy
solid at ca.–120° C, and the boiling point obtained by extrapolating the vapor‐pressure …

During the previous year, there has been substantial research into alkali metal
organometallics containing simple silanes. Daschlein et al. have used a variety of …