Merits and limitations of radical vs. nonradical pathways in persulfate-based advanced oxidation processes

Y Yan, Z Wei, X Duan, M Long, R Spinney… - Environmental …, 2023 - ACS Publications
Urbanization and industrialization have exerted significant adverse effects on water quality,
resulting in a growing need for reliable and eco-friendly treatment technologies. Persulfate …

A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation

N Li, J Ye, H Dai, P Shao, L Liang, L Kong, B Yan… - Water Research, 2023 - Elsevier
At present, numerous heterogeneous catalysts have been synthesized to activate persulfate
(PS) and produce various reactive species for antibiotic degradation from water. However …

Ultrafast degradation of emerging organic pollutants via activation of peroxymonosulfate over Fe3C/Fe@ NCx: Singlet oxygen evolution and electron-transfer …

C Zhao, L Meng, H Chu, JF Wang, T Wang, Y Ma… - Applied Catalysis B …, 2023 - Elsevier
Abstract Fe 3 C/Fe decorated N-doped magnetic carbon materials (denoted as Fe 3 C/Fe@
NC-x) were successfully fabricated via facile one-pot calcination of MIL-88B (Fe) with a …

Unveiling the Origins of Selective Oxidation in Single-Atom Catalysis via Co–N4–C Intensified Radical and Nonradical Pathways

M Yang, Z Hou, X Zhang, B Gao, Y Li… - Environmental …, 2022 - ACS Publications
Single-atom catalysts (SACs)-based peroxymonosulfate (PMS) systems are highly selective
to the type of organic pollutants while the mechanisms remain ambiguous. In this work, we …

Cobalt single atoms anchored on oxygen‐doped tubular carbon nitride for efficient peroxymonosulfate activation: simultaneous coordination structure and morphology …

Z Wang, E Almatrafi, H Wang, H Qin… - Angewandte …, 2022 - Wiley Online Library
Simultaneous regulation of the coordination environment of single‐atom catalysts (SACs)
and engineering architectures with efficient exposed active sites are efficient strategies for …

Electron delocalization triggers nonradical Fenton-like catalysis over spinel oxides

ZY Guo, Y Si, WQ Xia, F Wang, HQ Liu… - Proceedings of the …, 2022 - National Acad Sciences
Nonradical Fenton-like catalysis offers opportunities to overcome the low efficiency and
secondary pollution limitations of existing advanced oxidation decontamination …

Rational Regulation of Co–N–C Coordination for High-Efficiency Generation of 1O2 toward Nearly 100% Selective Degradation of Organic Pollutants

Y Yao, C Wang, X Yan, H Zhang, C Xiao… - Environmental …, 2022 - ACS Publications
Single oxygen-based advanced oxidation processes (1O2-AOPs) exhibit great prospects in
selective degradation of organic pollutants. However, efficient production of 1O2 via tailored …

Oxygen doping of cobalt-single-atom coordination enhances peroxymonosulfate activation and high-valent cobalt–oxo species formation

QY Wu, ZW Yang, ZW Wang… - Proceedings of the …, 2023 - National Acad Sciences
The high-valent cobalt–oxo species (Co (IV)= O) is being increasingly investigated for water
purification because of its high redox potential, long half-life, and antiinterference properties …

The debatable role of singlet oxygen in persulfate-based advanced oxidation processes

L Wang, K Xiao, H Zhao - Water Research, 2023 - Elsevier
Abstract Singlet oxygen (1 O 2) attracts much attention in persulfate-based advanced
oxidation processes (PS-AOPs), because of its wide pH tolerance and high selectivity …

Generation of FeIV=O and its Contribution to Fenton‐Like Reactions on a Single‐Atom Iron−N−C Catalyst

C Cheng, W Ren, F Miao, X Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Generating FeIV= O on single‐atom catalysts by Fenton‐like reaction has been established
for water treatment; however, the FeIV= O generation pathway and oxidation behavior …