Condensation-Based Methods for the C–H Bond Functionalization of Amines

W Chen, D Seidel - Synthesis, 2021 - thieme-connect.com
This review aims to provide a comprehensive overview of condensation-based methods for
the C–H bond functionalization of amines that feature azomethine ylides as key …

PIII/PV═O-Catalyzed Intermolecular N–N Bond Formation: Cross-Selective Reductive Coupling of Nitroarenes and Anilines

G Li, SP Miller, AT Radosevich - Journal of the American Chemical …, 2021 - ACS Publications
An organophosphorus-catalyzed method for the synthesis of unsymmetrical hydrazines by
cross-selective intermolecular N–N reductive coupling is reported. This method employs a …

N–N Bond Formation by a Small-Ring Phosphine Catalyst via the PIII/PV Cycle: Mechanistic Study and Guidelines to Obtain a Good Catalyst

S Zhang, R Gu, S Sakaki, G Zeng - ACS Catalysis, 2023 - ACS Publications
The mechanism of the N–N cross-coupling of nitroarene and aniline catalyzed by 1, 2, 2, 3,
4, 4-hexamethylphosphetane oxide (1PO) as well as the prediction of a better catalyst was …

Recent advances in the synthetic applications of nitrosoarene chemistry

F Lin, R Tang, S Liu, Y Tan - Organic & Biomolecular Chemistry, 2025 - pubs.rsc.org
Nitroso groups are widely present in biologically active compounds in medicinal chemistry,
and nitroso compounds serve as important building blocks in organic chemistry and …

Iminium and azonium-activated metal and oxidant-free C–H functionalization of aliphatic amines

N Ray, CK Jana - Chemical Communications, 2023 - pubs.rsc.org
A wide variety of synthetic methods have been developed for the synthesis of functionalized
aliphatic amines because of their broad utility in both synthetic and medicinal chemistry. The …

UV-Light-Induced Dehydrogenative N-Acylation of Amines with 2-Nitrobenzaldehydes to Give 2-Aminobenzamides

D Zeng, T Yang, N Tang, W Deng, J Xiang, SF Yin… - …, 2022 - thieme-connect.com
A simple, mild, green, and efficient method for the synthesis of 2-aminobenzamides is highly
desirable. Herein, we report the development of an efficient, one-pot strategy starting from 2 …

Density Functional Theory Study on the Mechanism of Iridium-Catalyzed Benzylamine ortho C–H Alkenylation with Ethyl Acrylate

J Wang, B Ling, P Liu, Y Liu, YY Jiang, S Bi - ACS omega, 2020 - ACS Publications
Iridium-catalyzed oxidative o-alkenylation of benzylamines with acrylates was enabled by
the directing group pentafluorobenzoyl (PFB). Density functional theory calculations were …

[引用][C] Unravelling the relative selectivity and mechanistic pathways towards product formation during copper-catalysed dehydrogenative cross-coupling of H …

EJ Itumoh - 2023 - ResearchSpace@ Auckland