Transition-metal catalyzed directing group (DG) assisted annulation of inert C–H bonds
leads to the formation of complex molecular frameworks from readily accessible substrates …

The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

Alkynes occupy a prominent role as a coupling partner in the transition metal-catalysed
directed C–H activation reactions. Due to low steric requirements and linear geometry …

A Ni-catalyzed C6 followed by C5 cascade C–H activation/[2+ 2+ 2] annulation of 2-pyridone
with alkynes has been achieved. A change in the reaction pathway was achieved by tuning …

Recently, transition metal‐catalyzed ortho‐C− H bond activation/annulations involving two
internal alkyne molecules have been extensively used to synthesize highly substituted …

An Ir (III)-catalyzed annulation of aryl amides with 1, 6-diynes via ortho-as well as meta-dual
C–H bond activation reaction is reported. The scope of the annulation reaction was …

Herein, one-pot cascade synthesis of chromeno [4, 3-c] pyrazol-4-ones and their Ru (II)-
catalyzed regioselective ortho-alkenylation using imine as a weak directing group are done …

The Ni (II)-catalyzed aromatic homologation of various directing groups with alkynes to
afford highly substituted naphthalene products via C–X bond cleavage followed by alkyne …

A nickel-catalyzed site-selective tandem cyclization of 1, 6-diynes with substituted indolines
or indoles through consecutive dual C–H bond activation is described. In the reaction …

The BF 3· OEt 2 promoted switchable synthesis of six-membered N-heterocycles and seven-
membered O-heterocycles from readily available feedstocks was developed by the …