Radical reactions of fullerenes: from synthetic organic chemistry to materials science and biology

MD Tzirakis, M Orfanopoulos - Chemical reviews, 2013 - ACS Publications
Since their discovery in 1985 1 and their production on a preparative scale 5 years later, 2
fullerenes have attracted a great deal of attention. Their chemical modification has emerged …

Remarkable diversity of carbon–carbon bonds: structures and properties of fullerenes, carbon nanotubes, and graphene

TC Dinadayalane, J Leszczynski - Structural Chemistry, 2010 - Springer
Large scientific community has been passionate in understanding different carbon
nanostructures for last two decades. In this review, we present the general description of low …

Chemistry of endohedral metallofullerenes: the role of metals

X Lu, T Akasaka, S Nagase - Chemical Communications, 2011 - pubs.rsc.org
Recent breakthroughs achieved in the chemical functionalization of endohedral
metallofullerenes (EMFs), especially single crystallographic X-ray characterizations of their …

Perfluoroalkylfullerenes

OV Boltalina, AA Popov, IV Kuvychko… - Chemical …, 2015 - ACS Publications
Perfluoroalkylfullerenes | Chemical Reviews ACS ACS Publications C&EN CAS Find my
institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most Read …

Electrochemical, Spectroscopic, and DFT Study of C60(CF3)n Frontier Orbitals (n = 2−18):  The Link between Double Bonds in Pentagons and Reduction …

AA Popov, IE Kareev, NB Shustova… - Journal of the …, 2007 - ACS Publications
The frontier orbitals of 22 isolated and characterized C60 (CF3) n derivatives, including
seven reported here for the first time, have been investigated by electronic spectroscopy (n …

The effect of hospital urine components on the degradation of ciprofloxacin during UV/chlorine disinfection process: Kinetics, pathways, and toxicity evaluation

Y Shao, X Li, L Jiang, X Wei, Y Zhao, X Chen… - Journal of Cleaner …, 2022 - Elsevier
UV/chlorine as an advanced oxidation process (AOPs) has been employed to treat
contaminants. However, current research has primarily focused on drinking water and …

Steric Scale of Common Substituents from Rotational Barriers of N-(o-Substituted aryl)thiazoline-2-thione Atropisomers

V Belot, D Farran, M Jean, M Albalat… - The Journal of …, 2017 - ACS Publications
A steric scale of 20 recurrent groups was established from comparison of rotational barriers
on N-(o-substituted aryl) thiazoline-2-thione atropisomers. The resulting energy of activation …

Sc2C2@C80 Rather than Sc2@C82: Templated Formation of Unexpected C2v(5)-C80 and Temperature-Dependent Dynamic Motion of Internal Sc2C2 …

H Kurihara, X Lu, Y Iiduka, N Mizorogi… - Journal of the …, 2011 - ACS Publications
Unambiguous X-ray crystallographic results of the carbene adduct of Sc2C82 reveal a new
carbide cluster metallofullerene with the unexpected C 2 v (5)-C80 cage, that is, Sc2C2@ C …

Organic chemistry of fullerenes: the major reactions, types of fullerene derivatives and prospects for practical use

PA Troshin, RN Lyubovskaya - Russian Chemical Reviews, 2008 - iopscience.iop.org
Data on the methods of functionalisation of C 60 and C 70 fullerenes published over the last
15 years are summarised. The general analysis of fullerene reactivity is performed …

Large Metal Ions in a Relatively Small Fullerene Cage: The Structure of Gd3N@C2(22010)-C78 Departs from the Isolated Pentagon Rule

CM Beavers, MN Chaur, MM Olmstead… - Journal of the …, 2009 - ACS Publications
An isomerically pure sample of Gd3N@ C78 has been extracted from the carbon soot
formed in the electric-arc generation of fullerenes using hollow graphite rods packed with …