Phosphines have played an important role in the rapid rise of transition metal-catalysed
processes and with the possibility of fine-tuning the electronic and steric properties of these …

Many methods have been developed for generating benzyne. Convenient and reliable
precursors extensively studied so far involve benzenediazonium-2-carboxylate and o …

This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

A simple and efficient protocol has been developed for the PdCl2-catalyzed ligand-free and
aerobic Suzuki reaction of aryl bromides or nitrogen-based heteroaryl bromides with …

A series of new imidazolium chlorides were straightforwardly prepared from the reactions
between chloroacetone and imidazole derivatives. Deprotonation of the methylene proton …

A convenient, new, and effective protocol for a rapid synthesis of different substituted 3-
arylcoumarins is reported. The developed synthetic route involves Pd-catalyzed cross …

The dienic nature of the aromatic π-system in 1, 4-diphosphinines remains largely
unexplored to this day due to a lack of facile and efficient synthetic protocols. Recently …

The synthesis of 2, 4, 6-triphenylphosphinine has been revisited and a general protocol for
the preparation of such low-coordinate phosphorus compounds in good to excellent yields …

Abstract The [4+ 2] cycloaddition of 2‐(2′‐pyridyl)‐4, 6‐diphenyl‐λ3‐phosphinine with the
highly reactive dienophile hexafluoro‐2‐butyne has been studied and the first pyridyl …

In situ generated Pd nanoparticles in the presence of N2, N4, N6-tridodecyl-1, 3, 5-triazine-
2, 4, 6-triamine (TDTAT) were found to be an efficient catalyst for the Suzuki–Miyaura …