Chemical reactions of organic compounds in supercritical water gasification and oxidation
N Wei, D Xu, B Hao, S Guo, Y Guo, S Wang - Water Research, 2021 - Elsevier
Supercritical water is a benign reaction medium to convert organic matters through
supercritical water gasification and supercritical water oxidation into flammable gaseous and …
supercritical water gasification and supercritical water oxidation into flammable gaseous and …
The chemistry of carbon in aqueous fluids at crustal and upper-mantle conditions: experimental and theoretical constraints
CE Manning, EL Shock… - Reviews in Mineralogy …, 2013 - pubs.geoscienceworld.org
Carbon can be a major constituent of crustal and mantle fluids, occurring both as dissolved
ionic species (eg, carbonate ions or organic acids) and molecular species (eg, CO2, CO …
ionic species (eg, carbonate ions or organic acids) and molecular species (eg, CO2, CO …
Experimental and theoretical investigation of alkene transformations in oceanic hydrothermal fluids: A mechanistic study of styrene
Natural organic matter plays an important role in oceanic hydrothermal systems through a
combination of geological and chemical processes. However, identifying the hydrothermal …
combination of geological and chemical processes. However, identifying the hydrothermal …
The mass spectrometer for planetary exploration (MASPEX)
TG Brockwell, KJ Meech, K Pickens… - 2016 IEEE …, 2016 - ieeexplore.ieee.org
The MASPEX instrument is a high-resolution, high-sensitivity time-of-flight mass
spectrometer developed for planetary applications. Its high-resolution (25,000 mMm at 10 …
spectrometer developed for planetary applications. Its high-resolution (25,000 mMm at 10 …
Soil processes modify the composition of volatile organic compounds (VOCs) from CO2-and CH4-dominated geogenic and landfill gases: A comprehensive study
Degradation mechanisms affecting non-methane volatile organic compounds (VOCs) during
gas uprising from different hypogenic sources to the surface were investigated through …
gas uprising from different hypogenic sources to the surface were investigated through …
Kinetics and mechanisms of dehydration of secondary alcohols under hydrothermal conditions
C Bockisch, ED Lorance, HE Hartnett… - ACS Earth and Space …, 2018 - ACS Publications
Alcohol dehydration by elimination of water is central to a series of functional group
interconversions that have been proposed as a reaction pathway that connects …
interconversions that have been proposed as a reaction pathway that connects …
Thermodynamics of organic transformations in hydrothermal fluids
Hydrothermal fluids obtain organic compounds through diverse pathways. In submarine
systems organic compounds are already dissolved in seawater that is heated and …
systems organic compounds are already dissolved in seawater that is heated and …
Direct synthesis of amides from amines and carboxylic acids under hydrothermal conditions
Hydrothermal systems provide a unique habitat for the subsurface biosphere, and possibly,
for the origin of life. Amides are fundamental to hydrothermal organic geochemistry and …
for the origin of life. Amides are fundamental to hydrothermal organic geochemistry and …
Quantifying the extent of amide and peptide bond synthesis across conditions relevant to geologic and planetary environments
KJ Robinson, C Bockisch, IR Gould, Y Liao… - … et Cosmochimica Acta, 2021 - Elsevier
Amide bonds are fundamental products in biochemistry, forming peptides critical to protein
formation, but amide bonds are also detected in sterile environments and abiotic synthesis …
formation, but amide bonds are also detected in sterile environments and abiotic synthesis …
Mechanisms of decarboxylation of phenylacetic acids and their sodium salts in water at high temperature and pressure
Mechanistic interpretations of how organic reactions happen can enhance the predictive
capacity of models for geochemical transformations built on thermodynamic and kinetic …
capacity of models for geochemical transformations built on thermodynamic and kinetic …