The significance of surface complexation reactions in hydrologic systems: a geochemist's perspective

C Koretsky - Journal of Hydrology, 2000 - Elsevier
Complexation reactions at the mineral–water interface affect the transport and
transformation of metals and organic contaminants, nutrient availability in soils, formation of …

The nature and partitioning of invisible gold in the pyrite-fluid system

GS Pokrovski, MA Kokh, O Proux, JL Hazemann… - Ore Geology …, 2019 - Elsevier
The most characteristic feature of hydrothermal deposits of gold is its intimate association
with pyrite. Microscopically visible gold occurs in pyrite ore as metal particles of> 0.1 µm in …

Scanning electrochemical microscopy

FRF Fan, B Liu, J Mauzeroll - Handbook of electrochemistry, 2007 - Elsevier
Publisher Summary The chapter discusses various techniques and applications of scanning
electrochemical microscopy (SECM), one of the scanning probe microscopies (SPM) in …

Arsenite sorption on troilite (FeS) and pyrite (FeS2)

BC Bostick, S Fendorf - Geochimica et cosmochimica Acta, 2003 - Elsevier
Arsenic is a toxic metalloid whose mobility and availability are largely controlled by sorption
on sulfide minerals in anoxic environments. Accordingly, we investigated reactions of As (III) …

X-ray photoelectron spectroscopic study of a pristine pyrite surface reacted with water vapour and air

HW Nesbitt, IJ Muir - Geochimica et Cosmochimica Acta, 1994 - Elsevier
Pristine pyrite fracture surfaces, exposed for 7 h to water vapour at low pressure (10− 5 Pa),
display no change to their Fe (2p) or S (2p) X-ray photoelectron (XPS) spectrum, but oxygen …

Interaction between aqueous uranium (VI) and sulfide minerals: spectroscopic evidence for sorption and reduction

P Wersin, MF Hochella Jr, P Persson, G Redden… - … et Cosmochimica Acta, 1994 - Elsevier
The interaction of aqueous U (VI) with galena and pyrite surfaces under anoxic conditions
has been studied by solution analysis and by spectroscopic methods. The solution data …

Understanding the mechanism of uranium removal from groundwater by zero-valent iron using X-ray photoelectron spectroscopy

JN Fiedor, WD Bostick, RJ Jarabek… - … Science & Technology, 1998 - ACS Publications
The contaminant of most concern in groundwater at the Oak Ridge Y-12 Plant's Bear Creek
Valley Characterization Area is soluble uranium. The removal mechanism of soluble …

Uranium uptake from aqueous solution by interaction with goethite, lepidocrocite, muscovite, and mackinawite: An X-ray absorption spectroscopy study

LN Moyes, RH Parkman, JM Charnock… - … science & technology, 2000 - ACS Publications
The retention of radionuclides by interaction with mineral phases has significant
consequences for the planning of their short-and long-term disposal to geological systems …

The disproportionation of gold (I) chloride complexes at 25 to 200 C

CH Gammons, Y Yu, AE Williams-Jones - Geochimica et Cosmochimica …, 1997 - Elsevier
The disproportionation of aqueous Au (I) chloride complexes at elevated temperature has
been investigated experimentally using the solubility method. At 300° C, the dominant gold …

The adsorption of gold (I) hydrosulphide complexes by iron sulphide surfaces

AM Widler, TM Seward - Geochimica et Cosmochimica Acta, 2002 - Elsevier
The adsorption of gold by pyrite, pyrrhotite, and mackinawite from solutions containing up to
40 mg/kg (8 μm) gold as hydrosulphidogold (I) complexes has been measured over the pH …