Direct functionalization processes: A journey from palladium to copper to iron to nickel to metal-free coupling reactions
JJ Mousseau, AB Charette - Accounts of Chemical Research, 2013 - ACS Publications
The possibility of finding novel disconnections for the efficient synthesis of organic
molecules has driven the interest in developing technologies to directly functionalize C–H …
molecules has driven the interest in developing technologies to directly functionalize C–H …
Direct C H Arylation of Heteroarenes Catalyzed by Palladium/Nitrogen‐Based Ligand Complexes
F Shibahara, T Murai - Asian Journal of Organic Chemistry, 2013 - Wiley Online Library
Significant progress has been made in transition‐metal‐catalyzed direct functionalization of
heteroarenes since the beginning of the 21st century. Particularly, palladium‐catalyzed …
heteroarenes since the beginning of the 21st century. Particularly, palladium‐catalyzed …
Reaching the south: metal-catalyzed transformation of the aromatic para-position
Regioselective functionalization of aromatic arenes has created a rapid insurgence in the
modern era of organic chemistry. While the last few years have witnessed significant …
modern era of organic chemistry. While the last few years have witnessed significant …
Potassium tert-Butoxide Promoted Intramolecular Arylation via a Radical Pathway
DS Roman, Y Takahashi, AB Charette - Organic letters, 2011 - ACS Publications
Potassium tert-butoxide mediated intramolecular cyclization of aryl ethers, amines, and
amides was efficiently performed under microwave irradiation to provide the corresponding …
amides was efficiently performed under microwave irradiation to provide the corresponding …
Palladium‐Catalyzed Double C H Activation Directed by Sulfoxides in the Synthesis of Dibenzothiophenes
R Samanta, AP Antonchick - Angewandte Chemie International Edition, 2011 - infona.pl
S O shows where to go: A novel double C H activation of aromatic compounds with a
sulfoxide as a directing group results in the highly regioselective synthesis of polysubstituted …
sulfoxide as a directing group results in the highly regioselective synthesis of polysubstituted …
Direct arylation of simple azoles catalyzed by 1, 10-phenanthroline containing palladium complexes: an investigation of C4 arylation of azoles and the synthesis of …
F Shibahara, E Yamaguchi, T Murai - The Journal of Organic …, 2011 - ACS Publications
Direct triarylation and sequential triarylation reactions of simple azoles catalyzed by [Pd
(phen) 2] PF6 are described. Simple azoles, such as N-methylimidazole, thiazole, and …
(phen) 2] PF6 are described. Simple azoles, such as N-methylimidazole, thiazole, and …
para-Selective arylation and alkenylation of monosubstituted arenes using thianthrene S-oxide as a transient mediator
XY Chen, XX Nie, Y Wu, P Wang - Chemical Communications, 2020 - pubs.rsc.org
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of
mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd …
mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd …
Free‐Amine‐Directed Alkenylation of C(sp2)H and Cycloamination by Palladium Catalysis
Z Liang, L Ju, Y Xie, L Huang… - Chemistry–A European …, 2012 - Wiley Online Library
A new protocol for the palladium‐catalyzed free‐amine‐directed alkenylation of C (sp2) H
bonds and cycloamination is described. Substituted biaryl‐2‐amines react with various …
bonds and cycloamination is described. Substituted biaryl‐2‐amines react with various …
Amide-Ligand-Controlled Highly para-Selective Arylation of Monosubstituted Simple Arenes with Arylboronic Acids
YX Luan, T Zhang, WW Yao, K Lu… - Journal of the …, 2017 - ACS Publications
Pd-catalyzed highly para-selective arylations of monosubstituted simple arenes with
arylboronic acids to widely existed biaryls have been developed. Inspired by requisite amide …
arylboronic acids to widely existed biaryls have been developed. Inspired by requisite amide …
Silver-promoted, palladium-catalyzed direct arylation of cyclopropanes: facile access to spiro 3, 3′-cyclopropyl oxindoles
CL Ladd, D Sustac Roman, AB Charette - Organic letters, 2013 - ACS Publications
The Pd-catalyzed, Ag (I)-mediated intramolecular direct arylation of cyclopropane C–H
bonds is described. Various spiro 3, 3′-cyclopropyl oxindoles can be obtained in good to …
bonds is described. Various spiro 3, 3′-cyclopropyl oxindoles can be obtained in good to …