Recent applications of acyclic (diene) iron complexes and (dienyl) iron cations in organic synthesis

WA Donaldson, S Chaudhury - European journal of organic …, 2009 - Wiley Online Library
Complexation of (tricarbonyl) iron to an acyclic diene serves to protect the ligand against
oxidation, reduction, and cycloaddition reactions, whereas the steric bulk of this adjunct …

Iron-Catalyzed Oxidative Sulfonylation of Enol Acetates: An Environmentally Benign Approach to β-Keto Sulfones

VK Yadav, VP Srivastava, LDS Yadav - Synlett, 2016 - thieme-connect.com
The first application of iron-catalyzed sulfonylation of aryl enol acetates with sulfonyl
hydrazides for the construction of β-keto sulfones under aerobic conditions is reported. The …

Nicholas Reactions in the Construction of Cyclohepta[de]naphthalenes and Cyclohepta[de]naphthalenones. The Total Synthesis of Microstegiol

RA Taj, JR Green - The Journal of Organic Chemistry, 2010 - ACS Publications
The application of the Nicholas reaction chemistry of 2, 7-dioxygenated naphthalenes in the
synthesis of cyclohepta [de] napthalenes and in the synthesis of (±)-microstegiol (1) is …

Iron-catalysed carbon–carbon single bond activation

JEMN Klein, B Plietker - Organic & Biomolecular Chemistry, 2013 - pubs.rsc.org
In search of recent challenges in synthetic organic chemistry transformations of substrates
possessing formally unreactive bonds have been thoroughly addressed. Amongst those …

Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)2I] and Aryl Grignard Reagents and Their Chemistry Directed toward …

S Yasuda, H Yorimitsu, K Oshima - Organometallics, 2008 - ACS Publications
Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)2I]
and Aryl Grignard Reagents and Their Chemistry Directed toward Organic Synthesis …

Catalytic Asymmetric Mannich‐Type Reactions Using a Novel Chiral Iron Complex

Y Yamashita, M Ueno, Y Kuriyama… - Advanced Synthesis & …, 2002 - Wiley Online Library
Catalytic asymmetric Mannich‐type reactions using a novel chiral iron complex have been
developed. The reactions proceeded smoothly in the presence of a catalyst prepared from …

N-Oxazolidinoyl Diene Iron(0) Tricarbonyl Complexes: Preparation by Diastereoselective Complexation and Synthetic Applications

RS Paley, BG Hejna, RE Quevedo, AR Wong… - …, 2022 - ACS Publications
We describe the synthesis of a family of chiral, nonracemic 3, 4-disubstituted 2-N-
oxazolidinoyl-1, 3-dienes (10 and 15a–15i) via Stille–Fürstner coupling. These chiral …

Iron (0) Tricarbonyl Complexes of Microbially Derived Cyclohexadiene Ligands Containing Quaternary Stereocenters

M Ali Khan, MF Mahon, AJW Stewart, SE Lewis - Organometallics, 2010 - ACS Publications
Tricarbonyliron (0) complexes of novel cyclohexadiene ligands possessing quaternary
centers have been synthesized and characterized by 1H and 13C NMR and by X-ray …

Valuable New Cyclohexadiene Building Blocks from Cationic η5‐Iron–Carbonyl Complexes Derived from a Microbial Arene Oxidation Product

M Ali Khan, MF Mahon, JP Lowe… - … A European Journal, 2012 - Wiley Online Library
Biooxidation of benzoic acid by Ralstonia eutropha B9 provides an unusual cyclohexadiene
carboxy diol that contains a quaternary stereocentre. Tricarbonyliron derivatives of this …

Total synthesis of muamvatin

DE Ward, MM Zahedi - Organic letters, 2012 - ACS Publications
Enantioselective total synthesis of muamvatin was achieved by ring-chain tautomerization of
an acyclic derivative assembled by sequential substrate-controlled stereoselective aldol …