Applications of Transition Metal-Catalyzed ortho-Fluorine-Directed C–H Functionalization of (Poly)fluoroarenes in Organic Synthesis

YP Budiman, RN Perutz, PG Steel, U Radius… - Chemical …, 2024 - ACS Publications
The synthesis of organic compounds efficiently via fewer steps but in higher yields is
desirable as this reduces energy and reagent use, waste production, and thus …

Remarkably flexible 2, 2′: 6′, 2 ″-terpyridines and their group 8–10 transition metal complexes–Chemistry and applications

RR Panicker, A Sivaramakrishna - Coordination Chemistry Reviews, 2022 - Elsevier
The main purpose of this article is to focus on the diversity created by substitution on
pyridine rings of 2, 2′: 6′, 2 ″-terpyridines (tpy) allowing a fine-tuning of the ligand …

Transition-metal-catalyzed silylation and borylation of C–H bonds for the synthesis and functionalization of complex molecules

IF Yu, JW Wilson, JF Hartwig - Chemical Reviews, 2023 - ACS Publications
The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Remote steric control for undirected meta-selective C–H activation of arenes

B Ramadoss, Y Jin, S Asako, L Ilies - Science, 2022 - science.org
Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …

CH Borylation: A Toolbox for Molecular Diversification

S Guria, MMM Hassan, B Chattopadhyay - Organic Chemistry …, 2024 - pubs.rsc.org
Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …

Cyclometallated complexes as catalysts for C–H activation and functionalization

JM Zakis, T Smejkal, J Wencel-Delord - Chemical Communications, 2022 - pubs.rsc.org
The development of novel catalysts for C–H activation reactions with increased reactivity
and improved selectivities has been attracting significant interest over the last two decades …

Development of Cobalt Catalysts for the meta-Selective C(sp2)–H Borylation of Fluorinated Arenes

TP Pabst, PJ Chirik - Journal of the American Chemical Society, 2022 - ACS Publications
Cobalt precatalysts for the meta-selective borylation of fluorinated arenes are described.
Initial screening and stoichiometric reactivity studies culminated in the preparation of a …

Fast and Selective β-C–H Borylation of N-Heterocycles with a Supramolecular Iridium Catalyst: Circumventing Deactivation Pathways and Mechanistic Insights

J Trouvé, P Rajeshwaran, M Tomasini… - ACS …, 2023 - ACS Publications
Selective iridium-catalyzed C–H bond borylations of unbiased or directing-group-free
substrates typically occur under long reaction times and mild temperatures in order to avoid …

Stimuli‐Induced Fluorescence Switching in Azine‐Containing Fluorophores Displaying Resonance‐Stabilized ESIPT Emission

T Stoerkler, G Ulrich, P Retailleau… - … A European Journal, 2024 - Wiley Online Library
This article reports the synthesis, along with structural and photophysical characterization of
2‐(2'‐hydroxyphenyl) benzazole derivatives functionalized with various azaheterocycles …

Ir-Catalyzed Ortho-Selective C–H Borylation of Difluoromethyl Arenes

CY Li, Z Zhang, X Yan - Organic Letters, 2023 - ACS Publications
The difluoromethyl group (CF2H) has received great attention due to its distinct properties in
recent years. Herein, we report a new strategy for postmodification of difluoromethyl …