The mechanochemical synthesis of polymers

A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

A guide to direct mechanocatalysis

S Hwang, S Grätz, L Borchardt - Chemical Communications, 2022 - pubs.rsc.org
Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …

Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides

T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …

Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions

S Lukin, K Užarević, I Halasz - Nature Protocols, 2021 - nature.com
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …

Tinkering with mechanochemical tools for scale up

JF Reynes, V Isoni, F García - … Chemie International Edition, 2023 - Wiley Online Library
Mechanochemistry provides an environmentally benign platform to develop more
sustainable chemical processes by limiting raw materials, energy use, and waste generation …

The Mechanochemical Synthesis and Activation of Carbon‐Rich π‐Conjugated Materials

M Xuan, C Schumacher, C Bolm, R Göstl… - Advanced …, 2022 - Wiley Online Library
Mechanochemistry uses mechanical force to break, form, and manipulate chemical bonds to
achieve functional transformations and syntheses. Over the last years, many innovative …

Eco-Friendly Production of Hyper-Cross-Linked Polymers Using Mechanosynthesis and Bioresources: A Critical Review

AM Borrero-López, A Celzard… - … Sustainable Chemistry & …, 2022 - ACS Publications
Hyper-cross-linked polymers (HCPs) are receiving great attention due to their high specific
surface areas, allowing them to offer high performances in many different applications …

Five-minute mechanosynthesis of hypercrosslinked microporous polymers

JSM Lee, T Kurihara, S Horike - Chemistry of Materials, 2020 - ACS Publications
Designable porous materials have potential in a plethora of applications, but synthesis costs
and strict reaction conditions limit their true commercialization. Herein, we show that …

From Inert to Catalytically Active Milling Media: Galvanostatic Coating for Direct Mechanocatalysis

M Wohlgemuth, M Mayer, M Rappen… - Angewandte Chemie …, 2022 - Wiley Online Library
The inert milling balls, commonly utilized in mechanochemical reactions, were coated with a
layer of Pd and utilized as catalyst in the direct mechanocatalytic Suzuki reaction. With high …

Mechanochemical synthesis of nitrogen-deficient mesopore-rich polymeric carbon nitride with highly enhanced photocatalytic performance

G Ba, T Huo, Q Deng, H Li, W Hou - ACS Sustainable Chemistry & …, 2020 - ACS Publications
Creation of defects and mesopores in polymeric carbon nitride (CN), a promising
photocatalyst for practical applications, is highly effective in enhancing the photocatalytic …