The mechanochemical synthesis of polymers
A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …
A guide to direct mechanocatalysis
S Hwang, S Grätz, L Borchardt - Chemical Communications, 2022 - pubs.rsc.org
Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …
Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides
T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …
Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …
Tinkering with mechanochemical tools for scale up
Mechanochemistry provides an environmentally benign platform to develop more
sustainable chemical processes by limiting raw materials, energy use, and waste generation …
sustainable chemical processes by limiting raw materials, energy use, and waste generation …
The Mechanochemical Synthesis and Activation of Carbon‐Rich π‐Conjugated Materials
Mechanochemistry uses mechanical force to break, form, and manipulate chemical bonds to
achieve functional transformations and syntheses. Over the last years, many innovative …
achieve functional transformations and syntheses. Over the last years, many innovative …
Eco-Friendly Production of Hyper-Cross-Linked Polymers Using Mechanosynthesis and Bioresources: A Critical Review
AM Borrero-López, A Celzard… - … Sustainable Chemistry & …, 2022 - ACS Publications
Hyper-cross-linked polymers (HCPs) are receiving great attention due to their high specific
surface areas, allowing them to offer high performances in many different applications …
surface areas, allowing them to offer high performances in many different applications …
Five-minute mechanosynthesis of hypercrosslinked microporous polymers
Designable porous materials have potential in a plethora of applications, but synthesis costs
and strict reaction conditions limit their true commercialization. Herein, we show that …
and strict reaction conditions limit their true commercialization. Herein, we show that …
From Inert to Catalytically Active Milling Media: Galvanostatic Coating for Direct Mechanocatalysis
M Wohlgemuth, M Mayer, M Rappen… - Angewandte Chemie …, 2022 - Wiley Online Library
The inert milling balls, commonly utilized in mechanochemical reactions, were coated with a
layer of Pd and utilized as catalyst in the direct mechanocatalytic Suzuki reaction. With high …
layer of Pd and utilized as catalyst in the direct mechanocatalytic Suzuki reaction. With high …
Mechanochemical synthesis of nitrogen-deficient mesopore-rich polymeric carbon nitride with highly enhanced photocatalytic performance
G Ba, T Huo, Q Deng, H Li, W Hou - ACS Sustainable Chemistry & …, 2020 - ACS Publications
Creation of defects and mesopores in polymeric carbon nitride (CN), a promising
photocatalyst for practical applications, is highly effective in enhancing the photocatalytic …
photocatalyst for practical applications, is highly effective in enhancing the photocatalytic …