Indium (III) as π-acid catalyst for the electrophilic activation of carbon–carbon unsaturated systems
JP Sestelo, LA Sarandeses, MM Martínez… - Organic & …, 2018 - pubs.rsc.org
This review focuses on the utilization of indium (III) as π-acid for the activation of C–C
unsaturated bonds in organic synthesis. In addition to its well-known σ-coordination with …
unsaturated bonds in organic synthesis. In addition to its well-known σ-coordination with …
InCl3: A Versatile Catalyst for Synthesizing a Broad Spectrum of Heterocycles
This review deals with the recent applications of the indium trichloride (InCl3) catalyst in the
synthesis of a broad spectrum of heterocyclic compounds. Over the years, a number of …
synthesis of a broad spectrum of heterocyclic compounds. Over the years, a number of …
Rethinking the Lewis Acidity of Cationic Gallium and Indium Catalysts
C Goonesinghe, HJ Jung, IO Betinol, JR Gaffen… - ACS …, 2023 - ACS Publications
Indium compounds are commonly considered weaker Lewis acids than their gallium
counterparts. We explore the difference in Lewis acidity of the cationic dialkylgallium [GaR2 …
counterparts. We explore the difference in Lewis acidity of the cationic dialkylgallium [GaR2 …
Indium(III)-Catalyzed Synthesis of Benzo[b]furans by Intramolecular Hydroalkoxylation of ortho-Alkynylphenols: Scope and Mechanistic Insights
L Alonso-Marañón, MM Martínez… - The Journal of …, 2018 - ACS Publications
Indium (III) halides catalyze the hydroalkoxylation reaction of ortho-alkynylphenols to afford
benzo [b] furans in good yields. The reaction proceeds with 5-endo-dig regioselectivity with …
benzo [b] furans in good yields. The reaction proceeds with 5-endo-dig regioselectivity with …
Magnetic cellulose nanocrystals as efficient support for indium (III) in the synthesis of tetrazoles and phthalazines
Catalysts, especially heterogeneous catalysts, play an essential role in organic
transformation reactions. Hence, we use a composite of cellulose nanocrystals (CNC) and …
transformation reactions. Hence, we use a composite of cellulose nanocrystals (CNC) and …
Combined Lewis Acid Catalyzed Diastereoselective Halogenative Cascade Annulation of Enone-Tethered Cyclohexadienones
T Nallamilli, A Munakala, R Chegondi - Organic Letters, 2023 - ACS Publications
The cascade difunctionalization of α, β-unsaturated carbonyls by nucleophilic halogenation
followed by enolate trapping with other electrophiles is highly challenging in synthetic …
followed by enolate trapping with other electrophiles is highly challenging in synthetic …
Indium (iii)-catalyzed stereoselective synthesis of tricyclic frameworks by cascade cycloisomerization reactions of aryl 1, 5-enynes
RE Millán, J Rodríguez, LA Sarandeses… - The Journal of …, 2021 - ACS Publications
The indium (III)-catalyzed cascade cycloisomerization reaction of 1, 5-enynes with pendant
aryl nucleophiles is reported. The reaction proceeds in cascade under mild reaction …
aryl nucleophiles is reported. The reaction proceeds in cascade under mild reaction …
Carbometalation and Heterometalation of Carbon‐Carbon Multiple‐Bonds Using Group‐13 Heavy Metals: Carbogallation, Carboindation, Heterogallation, and …
Y Nishimoto, M Yasuda - Chemistry–An Asian Journal, 2020 - Wiley Online Library
Organogallium and‐indium compounds are useful reagents in organic synthesis because of
their moderate stability, efficient reactivity and high chemoselectivity. Carbogallation and …
their moderate stability, efficient reactivity and high chemoselectivity. Carbogallation and …
Synthesis and Characterization of Tetrakis (pentafluoroethyl) indate Salts
S Porath, M Keßler, B Neumann… - … A European Journal, 2023 - Wiley Online Library
In the rising field of organoindium chemistry little is known about the perfluoroorganyl‐
substituted indium compounds. The increasing use of indium reagents is explained by their …
substituted indium compounds. The increasing use of indium reagents is explained by their …
[HTML][HTML] Formal insertion of selenoketenes into donor–acceptor cyclopropanes: mesomeric alkynylselenolates as key starting materials
Donor–acceptor cyclopropanes (DACs) react with lithium alkynylselenolates in the presence
of In (OTf) 3 to furnish tetrahydroselenophenes with exocyclic double bonds. The reaction …
of In (OTf) 3 to furnish tetrahydroselenophenes with exocyclic double bonds. The reaction …