Proton reduction is a critical reaction for the efficient utilization of solar fuels and the
development of a hydrogen economy. Molecular proton reduction catalysts help us to …

The production of hydrogen gas using water as the molecular substrate currently represents
one of the most challenging and appealing reaction schemes in the field of artificial …

Molecular design to improve catalyst performance is significant but challenging. In enzymes,
residue groups that are close to reaction centers play critical roles in regulating activities …

A nickel (II) porphyrin Ni‐P (P= porphyrin) bearing four meso‐C6F5 groups to improve
solubility and activity was used to explore different hydrogen‐evolution‐reaction (HER) …

Structural modifications of molecular cobalt catalysts have provided important insights into
the structure–function relationship for the hydrogen evolution reaction. We have shown that …

Abstract A cobalt complex of 5, 15‐bis (pentafluorophenyl)‐10‐(4)‐(1‐pyrenyl) phenyl
corrole that contains a triphenylphosphine axial ligand (1‐PPh3) was synthesized and …

GaIII chloride tetrakis (pentafluorophenyl) porphyrin (1) was synthesized and shown to be a
highly active and stable post-transition metal-based electrocatalyst for the hydrogen …

Electrocatalytic proton reduction to form dihydrogen (H2) is an effective way to store energy
in the form of chemical bonds. In this study, we validate the applicability of a main‐group …

The thermodynamic favorability of an alkaline solution for the oxidation of water suggests the
need for developing hydrogen evolution reaction (HER) catalysts that can function in basic …

For public health and environmental protection reasons, there is an urgent need to replace
traditional fossil fuels with clean and renewable sources. Electrochemical splitting of water …