Nucleophilic Thiol-yne reaction in Macromolecular Engineering: From synthesis to applications

O Daglar, S Luleburgaz, E Baysak, US Gunay… - European Polymer …, 2020 - Elsevier
The developments in synthetic polymer chemistry have devoted to meet the huge demand
required to create efficient, high yield, and operationally simple chemical methods that can …

Synthesis and iodine adsorption properties of organometallic copolymers with propeller-shaped Fe (II) clathrochelates bridged by different diaryl thioether and their …

S Shetty, N Baig, B Alameddine - Polymers, 2022 - mdpi.com
Three organometallic copolymers, ICP1-3, containing iron (II) clathrochelate units with
cyclohexyl lateral groups and interconnected by various thioether derivatives were …

Conjugated microporous polymers using a copper-catalyzed [4+ 2] cyclobenzannulation reaction: promising materials for iodine and dye adsorption

N Baig, S Shetty, S Al-Mousawi, B Alameddine - Polymer Chemistry, 2021 - pubs.rsc.org
A design strategy is disclosed to synthesize conjugated microporous polymers (CMPs) using
a versatile copper-catalyzed [4+ 2] cyclobenzannulation reaction, which employs a …

Synthesis of iron (II) clathrochelate-based Poly (vinylene sulfide) with tetraphenylbenzene bridging units and their selective oxidation into their corresponding poly …

N Baig, S Shetty, SS Habib, AA Husain, S Al-Mousawi… - Polymers, 2022 - mdpi.com
The development of a simple and efficient synthetic methodology to engineer functional
polymer materials for gas adsorption is necessary due to its relevance for various …

Synthesis of conjugated polymers via cyclopentannulation reaction: Promising materials for iodine adsorption

N Baig, S Shetty, S Al-Mousawi, B Alameddine - Polymer Chemistry, 2020 - pubs.rsc.org
A new class of conjugated polymers is prepared by means of a versatile palladium-
catalyzed cyclopentannulation reaction using a series of specially designed diethynyl aryl …

Thiol‐yne 3D printable polymeric resins for the efficient removal of a model pollutant from waters

L Shahzadi, F Maya, MC Breadmore… - Macromolecular …, 2023 - Wiley Online Library
A new 3D printable resin formulation is developed and optimized from commercially
available thiol (pentaerythritol tetrakis (3‐mercaptopropionate); PETMP) and alkyne (3 …

Selective removal of toxic organic dyes using Trӧger base-containing sulfone copolymers made from a metal-free thiol-yne click reaction followed by oxidation

N Baig, S Shetty, MS Moustafa, S Al-Mousawi… - RSC …, 2021 - pubs.rsc.org
Three copolymers TCP1–3 bearing Trӧger's base (TB) units intercalated with various
thioether groups were synthesized using a catalyst-free thiol-yne click reaction. TCP1–3 …

Synthesis of metalorganic copolymers containing various contorted units and iron (II) clathrochelates with lateral butyl chains: conspicuous adsorbents of lithium ions …

S Shetty, N Baig, MS Moustafa, S Al-Mousawi… - Polymers, 2022 - mdpi.com
We report the synthesis of three highly soluble metalorganic copolymers, TCP1–3, that were
made from a one-pot complexation of iron (II) clathrochelate units that are interconnected by …

[HTML][HTML] Tailor-made poly (vinylidene sulfide) s by Rh (I)–NHC catalyzed regioselective thiol-yne click polymerization

P Hermosilla, D Funes-Hernando, R Castarlenas… - European Polymer …, 2023 - Elsevier
Abstract The [Rh (μ-Cl)(IPr)(η 2-coe)] 2/pyridine system efficiently catalyzes the
polyhydrothiolation of a series of dialkynes with dithiols, producing sulfur-rich poly …

Preparation of superhydrophobic nylon-56/cotton-interwoven fabric with dopamine-assisted use of thiol–ene click chemistry

B Wang, C Gao, Y Huang, Z Xu, Y Zhang, Q Yang… - RSC …, 2021 - pubs.rsc.org
With the help of dopamine, we constructed a hydroxyl-rich secondary reaction platform on a
surface formed by interwoven nylon 56 and cotton fibres. Octadecyl mercaptan and vinyl …