The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Polariton chemistry: controlling molecular dynamics with optical cavities

RF Ribeiro, LA Martínez-Martínez, M Du… - Chemical …, 2018 - pubs.rsc.org
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …

Strong light–matter interactions: a new direction within chemistry

M Hertzog, M Wang, J Mony, K Börjesson - Chemical Society Reviews, 2019 - pubs.rsc.org
It is possible to modify the chemical and physical properties of molecules, not only through
chemical modifications but also by coupling molecules strongly to light. More intriguingly …

Cavity-controlled chemistry in molecular ensembles

F Herrera, FC Spano - Physical Review Letters, 2016 - APS
The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic
molecules has opened new routes to control chemical dynamics at the nanoscale. We show …

Multiple Rabi splittings under ultrastrong vibrational coupling

J George, T Chervy, A Shalabney, E Devaux, H Hiura… - Physical review …, 2016 - APS
From the high vibrational dipolar strength offered by molecular liquids, we demonstrate that
a molecular vibration can be ultrastrongly coupled to multiple IR cavity modes, with Rabi …

Theory of nanoscale organic cavities: The essential role of vibration-photon dressed states

F Herrera, FC Spano - ACS photonics, 2018 - ACS Publications
The interaction of organic molecules and molecular aggregates with electromagnetic fields
that are strongly confined in nanoscale optical cavities has allowed the observation of exotic …

Absorption and photoluminescence in organic cavity QED

F Herrera, FC Spano - Physical Review A, 2017 - APS
Organic microcavities can be engineered to reach exotic quantum regimes of strong and
ultrastrong light-matter coupling. However, the microscopic interpretation of their …

Strong light-matter coupling and hybridization of molecular vibrations in a low-loss infrared microcavity

M Muallem, A Palatnik, GD Nessim… - The journal of physical …, 2016 - ACS Publications
Hybridized polaritons are generated by simultaneously coupling two vibrational modes of
two different organic materials to the resonance of a low-loss infrared optical microcavity. A …

Vibrational coupling of water from weak to ultrastrong coupling regime via cavity mode tuning

T Fukushima, S Yoshimitsu… - The Journal of Physical …, 2021 - ACS Publications
Vibrational strong coupling is an emerging method for modulation of ground-state molecular
properties. Spectroscopic information about the vibrational coupling state is essential for …