The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Vibration-cavity polariton chemistry and dynamics
AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …
molecular electronic or vibrational transitions. When the coupling is strong enough, new …
Polariton chemistry: controlling molecular dynamics with optical cavities
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …
Strong light–matter interactions: a new direction within chemistry
It is possible to modify the chemical and physical properties of molecules, not only through
chemical modifications but also by coupling molecules strongly to light. More intriguingly …
chemical modifications but also by coupling molecules strongly to light. More intriguingly …
Cavity-controlled chemistry in molecular ensembles
The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic
molecules has opened new routes to control chemical dynamics at the nanoscale. We show …
molecules has opened new routes to control chemical dynamics at the nanoscale. We show …
Multiple Rabi splittings under ultrastrong vibrational coupling
From the high vibrational dipolar strength offered by molecular liquids, we demonstrate that
a molecular vibration can be ultrastrongly coupled to multiple IR cavity modes, with Rabi …
a molecular vibration can be ultrastrongly coupled to multiple IR cavity modes, with Rabi …
Theory of nanoscale organic cavities: The essential role of vibration-photon dressed states
The interaction of organic molecules and molecular aggregates with electromagnetic fields
that are strongly confined in nanoscale optical cavities has allowed the observation of exotic …
that are strongly confined in nanoscale optical cavities has allowed the observation of exotic …
Absorption and photoluminescence in organic cavity QED
Organic microcavities can be engineered to reach exotic quantum regimes of strong and
ultrastrong light-matter coupling. However, the microscopic interpretation of their …
ultrastrong light-matter coupling. However, the microscopic interpretation of their …
Strong light-matter coupling and hybridization of molecular vibrations in a low-loss infrared microcavity
M Muallem, A Palatnik, GD Nessim… - The journal of physical …, 2016 - ACS Publications
Hybridized polaritons are generated by simultaneously coupling two vibrational modes of
two different organic materials to the resonance of a low-loss infrared optical microcavity. A …
two different organic materials to the resonance of a low-loss infrared optical microcavity. A …
Vibrational coupling of water from weak to ultrastrong coupling regime via cavity mode tuning
T Fukushima, S Yoshimitsu… - The Journal of Physical …, 2021 - ACS Publications
Vibrational strong coupling is an emerging method for modulation of ground-state molecular
properties. Spectroscopic information about the vibrational coupling state is essential for …
properties. Spectroscopic information about the vibrational coupling state is essential for …