Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …

Nucleus-independent chemical shifts (NICS) as an aromaticity criterion

Z Chen, CS Wannere, C Corminboeuf, R Puchta… - Chemical …, 2005 - ACS Publications
Few concepts are as frequently used as aromaticity in the current chemical literature. 1 This
may be quantified by ca. 300 000 papers dealing with the aromatic properties of chemical …

Photochemical reactions as key steps in organic synthesis

N Hoffmann - Chemical Reviews, 2008 - ACS Publications
Since the beginning of scientific chemistry, chemists have been interested in light as an
energy source to induce chemical reactions. 1 Absorbing light, molecules reach an …

The gauge including magnetically induced current method

H Fliegl, S Taubert, O Lehtonen… - Physical Chemistry …, 2011 - pubs.rsc.org
An overview of applications of the recently developed gauge including magnetically induced
current method (GIMIC) is presented. The GIMIC method is used to obtain magnetically …

Ball-, bowl-, and belt-shaped conjugated systems and their complexing abilities: exploration of the concave− convex π− π interaction

T Kawase, H Kurata - Chemical reviews, 2006 - ACS Publications
Since the discovery of buckminsterfullerene C60 (Chart 1) by Kroto, Smalley, and Curl, 1-4 a
number of reports concerning new carbon allotropes having a variety of threedimensional …

Topology in chemistry: designing Möbius molecules

R Herges - Chemical reviews, 2006 - ACS Publications
In 1747, Johann Sebastian Bach wrote a series of canons and fugues on the occasion of his
visit to King Frederick the Great of Prussia in Potsdam. His music of homage, the …

Synthesis of belt-and Möbius-shaped cycloparaphenylenes by rhodium-catalyzed alkyne cyclotrimerization

S Nishigaki, Y Shibata, A Nakajima… - Journal of the …, 2019 - ACS Publications
A belt-shaped [8] cycloparaphenylene (CPP) and an enantioenriched Möbius-shaped [10]
CPP have been synthesized by high-yielding rhodium-catalyzed intramolecular …

[图书][B] Aromaticity: Modern Computational Methods and Applications

I Fernández - 2021 - books.google.com
Evaluating the aromaticity of a molecular system and the influence of this concept on its
properties is a crucial step in the development of novel aromatic systems. Modern …

Möbius aromaticity and delocalization

HS Rzepa - Chemical reviews, 2005 - ACS Publications
The Möbius strip is named after the theoretical astronomer and mathematician August
Ferdinand Möbius (1790-1868). In a memoir, presented to the French Academie of …

Möbius aromaticity and antiaromaticity in expanded porphyrins

ZS Yoon, A Osuka, D Kim - Nature chemistry, 2009 - nature.com
Aromaticity is a key concept in chemistry, dating back to Faraday's discovery of benzene in
1825 and Kekulé's famous alternating-double-bond structure of 1865. In 1858, the Möbius …