A convenient one-pot synthesis, and characterisation of the ω-bromo-1-(4-cyanobiphenyl-4'-yl) alkanes (CBnBr)

CJ Gibb, JMD Storey, CT Imrie - Liquid Crystals, 2022 - Taylor & Francis
ABSTRACT A convenient synthetic route based on a sodium-mediated aromatic cross-
coupling reaction is described for the multi-gram preparation of the ω-bromo-1-(4 …

Calculated physicochemical properties of glycerol-derived solvents to drive plastic waste recycling

A Soyemi, T Szilvási - Industrial & Engineering Chemistry …, 2023 - ACS Publications
Plastic waste has become a major environmental crisis, with the majority of plastic being
produced ending up in open landfills and waterways every year. Solvent-based recycling …

Room temperature nematic liquid crystals: Synthesis and characterisation of pentabromophenol and cyanobiphenyl derived rod-shaped molecules

HT Srinivasa, LM Rahman - Liquid Crystals, 2023 - Taylor & Francis
Calamitic molecules consisting of pentabromophenol tethered to cyanobiphenyl via a
flexible alkyl chain were synthesised and characterised for their mesomorphic properties …

Synthesis and microwave dielectric properties of polyphenylene liquid crystal compounds with lateral substitution by methyl and fluorine

H Liu, M Liu, S Gao, Z Zhang, X Wang, J Guan… - Liquid …, 2021 - Taylor & Francis
Nematic liquid crystals are promising materials for microwave communication owing to their
continuous tunability as dielectrics and wide frequency range selection. However …

Influence of multifluorophenyloxy terminus on the mesomorphism of the alkoxy and alkyl cyanobiphenyl compounds in search of new ambient nematic liquid crystals …

K Wang, MS Rahman, T Szilvási, JI Gold, N Bao… - Liquid …, 2021 - Taylor & Francis
ABSTRACT A series of cyanobiphenyl (CB) and cyano-p-terphenyl (CT) derivatives
containing a variety of highly fluorinated aryloxyl termini and different connecting bridges …

Influence of monohalogenated flexible tails on the mesomorphism of triphenylene-based discotics

Y Wang, W Bi, S Zhao, Y Liu, K Wang, S Xu, S Cao - Tetrahedron, 2023 - Elsevier
A series of triphenylene-based discotic liquid crystals (DLCs) modified by fluorination or
chlorination at the end of peripheral flexible chains were examined in this work. DLC …

Investigation of the mesogenic behavior of alkoxy and fluorine tail terminated alkoxy nitrobiphenyls for chemoresponsive liquid crystals

MS Rahman, T Wolter, A Tripathi, NL Abbott… - Liquid …, 2022 - Taylor & Francis
Liquid crystal properties of compounds with a variety of polar terminal groups including
cyano, fluoro, isothiocyanato, etc., were studied well, however, not enough attention was …

Predicting the melting point of liquid crystals with directed message passing neural networks

A Soyemi, SK Pandey, SA Vaara, T Szilvási - Liquid Crystals, 2024 - Taylor & Francis
Liquid crystal (LC) phases must exist in an appropriate temperature range for practical
applications and thus the melting point (MP) is a critical design target of LCs. In this work, we …

Synthesis and examination of alkoxycyanobiphenyl mesogens with a single fluorine atom at specific locations in the tail

K Agrahari, TJ Wolter, E Smith, NL Abbott… - Liquid …, 2024 - Taylor & Francis
Selective fluorination is a well-established technique to tailor and improve many of the
physical properties of liquid crystals. Cyanobiphenyls are among the best-known and …

Synthesis, characterisation and comparative study of the hydroxyl, acrylate and vinyl-ether terminated cyanobiphenyl bridged with different spacer lengths

S Zhang, T Zhong, Q Wang, C Li, X Wang, L Zhang… - Liquid …, 2021 - Taylor & Francis
Three homologous series hydroxyl, acrylate and vinyl-ether terminated cyanobiphenyl
compounds have been synthesised, termed as nOCB-OH, nOCB-AE and nOCB-VE (n= 2 …