Ozonolysis is a major tropospheric removal mechanism for unsaturated hydrocarbons and
proceeds via “Criegee intermediates”—carbonyl oxides—that play a key role in tropospheric …

Although carbonyl oxides,“Criegee intermediates,” have long been implicated in
tropospheric oxidation, there have been few direct measurements of their kinetics, and only …

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Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …

The Criegee intermediates are carbonyl oxides postulated to play key roles in the reactions
of ozone with unsaturated hydrocarbons; these reactions constitute an important mechanism …

The chemistry of carbonyl oxides, known as Criegee intermediates, is central to many
aspects of tropospheric chemistry. For decades it has been known that these reactive …

In this paper we report the detection and identification of the keto-hydroperoxide
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized …

Ozonolysis of alkenes, an important nonphotolytic source of hydroxyl (OH) radicals in the
troposphere, proceeds through energized Criegee intermediates that undergo unimolecular …

Carbonyl oxide species play a key role in tropospheric oxidation of organic molecules and in
low-temperature combustion processes. In the late 1940s, Criegee first postulated the …

Criegee intermediates, which are carbonyl oxides produced when ozone reacts with
unsaturated hydrocarbons, play an important role in the formation of OH and organic acids …