Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Light in gold catalysis

S Witzel, ASK Hashmi, J Xie - Chemical Reviews, 2021 - ACS Publications
Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …

Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Homogeneous gold-catalyzed oxidation reactions

Z Zheng, X Ma, X Cheng, K Zhao, K Gutman… - Chemical …, 2021 - ACS Publications
Homogeneous gold catalysis has experienced extraordinary development since the dawn of
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …

The merger of transition metal and photocatalysis

J Twilton, C Le, P Zhang, MH Shaw, RW Evans… - Nature Reviews …, 2017 - nature.com
The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis,
has recently emerged as a versatile platform for the development of new, highly enabling …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Merging visible light photoredox and gold catalysis

MN Hopkinson, A Tlahuext-Aca… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Since the beginning of this century, π-Lewis acidic gold complexes have
become the catalysts of choice for a wide range of organic reactions, especially those …

Rational development of catalytic Au (I)/Au (III) arylation involving mild oxidative addition of aryl halides

A Zeineddine, L Estévez, S Mallet-Ladeira… - Nature …, 2017 - nature.com
The reluctance of gold to achieve oxidative addition reaction is considered as an intrinsic
limitation for the development of gold-catalyzed cross-coupling reactions with simple and …

Biaryl synthesis with arenediazonium salts: cross-coupling, CH-arylation and annulation reactions

FX Felpin, S Sengupta - Chemical Society Reviews, 2019 - pubs.rsc.org
The rich legacy of arenediazonium salts in the synthesis of unsymmetrical biaryls, built
around the seminal works of Pschorr, Gomberg and Bachmann more than a century ago …

Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions

MO Akram, S Banerjee, SS Saswade, V Bedi… - Chemical …, 2018 - pubs.rsc.org
The construction of C–C and C–X (X= hetero atom) bonds is the core aspect for the
assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling …