[HTML][HTML] Porous framework materials for energy & environment relevant applications: A systematic review

Y Liu, L Chen, L Yang, T Lan, H Wang, C Hu… - Green Energy & …, 2024 - Elsevier
Carbon peaking and carbon neutralization trigger a technical revolution in energy &
environment related fields. Development of new technologies for green energy production …

Photocatalysis meets confinement: an emerging opportunity for photoinduced organic transformations

Y Hao, YL Lu, Z Jiao, CY Su - … Chemie International Edition, 2024 - Wiley Online Library
The self‐assembled metal‐organic cages (MOCs) have been evolved as a paradigm of
enzyme‐mimic catalysts since they are able to synergize multifunctionalities inherent in …

A Redox-Active Supramolecular Fe4L6 Cage Based on Organic Vertices with Acid–Base-Dependent Charge Tunability for Dehydrogenation Catalysis

YL Lu, JQ Song, YH Qin, J Guo, YH Huang… - Journal of the …, 2022 - ACS Publications
Supramolecular cage chemistry is of lasting interest because, as artificial blueprints of
natural enzymes, the self-assembled cage structures not only provide substrate-hosting …

Elaborating E/Z‐Geometry of Alkenes via Cage‐Confined Arylation Catalysis of Terminal Olefins

Y Wang, J Chen, J Yang, Z Jiao… - Angewandte Chemie …, 2023 - Wiley Online Library
A visible light photosensitizing metal‐organic cage is applied as an artificial supramolecular
reactor to control the reaction of aryl radicals with terminal olefins under green light/solvent …

Chiral Molecular Cage with Tunable Stereoinversion Barriers

WB Gao, Z Li, T Tong, X Dong, H Qu… - Journal of the …, 2023 - ACS Publications
The manipulation of chirality in molecular entities that rapidly interconvert between
enantiomeric forms is challenging, particularly at the supramolecular level. Advances in …

[HTML][HTML] A robust protein-mimicking metallo-amine cage showing proton-driven allostery with water as the effector

YL Lu, XD Zhang, YH Qin, JQ Song, YH Huang, CH Liu… - Chem, 2023 - cell.com
The allosteric effect is omnipresent in proteins with two distinct binding sites communicating
over a distance to control biological functions and complex processes, which drives an …

Constructing Ultrastable Metallo-Cages via In Situ Deprotonation/Oxidation of Dynamic Supramolecular Assemblies

P Su, W Zhang, C Guo, H Liu, C Xiong… - Journal of the …, 2023 - ACS Publications
Coordination-driven self-assembly enables the spontaneous construction of metallo-
supramolecules with high precision, facilitated by dynamic and reversible metal–ligand …

Regulating interlayer spacing of aminated graphene oxide membranes for efficient flow reactions

S Pang, D Peng, Y Hao, B Song, X Zhang, L Jiang - Matter, 2023 - cell.com
Nanoconfinement effect can significantly impact chemical reactivity. Chemists design
various porous nanoconfined systems to catalyze reactions. However, using these artificial …

Stereocontrolled Self-Assembly of a Helicate-Bridged CuI12L4 Cage That Emits Circularly Polarized Light

H Zhu, L Pesce, R Chowdhury, W Xue… - Journal of the …, 2024 - ACS Publications
Control over the stereochemistry of metal–organic cages can give rise to useful functions
that are entwined with chirality, such as stereoselective guest binding and chiroptical …

A Diverse Array of Large Capsules Transform in Response to Stimuli

K Wu, TK Ronson, L Goh, W Xue… - Journal of the …, 2023 - ACS Publications
The allosteric regulation of biomolecules, such as enzymes, enables them to adapt and alter
their conformation to fit specific substrates, expressing different functionalities in response to …