Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces
B van Genabeek, BAG Lamers… - Journal of Polymer …, 2021 - Wiley Online Library
Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …
various applications as well as fundamental studies. Notably, this field of science which can …
[HTML][HTML] The current science of sequence-defined macromolecules
A fundamental endeavour in macromolecular science is the control of molecular-level
complexity, including molecular weight distribution, end groups and architecture. Since the …
complexity, including molecular weight distribution, end groups and architecture. Since the …
Single unit monomer insertion: a versatile platform for molecular engineering through radical addition reactions and polymerization
J Xu - Macromolecules, 2019 - ACS Publications
Single unit monomer insertion (SUMI) is an emerging technology for precise polymer
synthesis through a radical addition reaction mechanism with monomer additions occurring …
synthesis through a radical addition reaction mechanism with monomer additions occurring …
[HTML][HTML] Precise control of conjugated polymer synthesis from step-growth polymerization to iterative synthesis
C Xu, J Dong, C He, J Yun, X Pan - Giant, 2023 - Elsevier
Conjugated polymers with excellent optoelectronic properties, easy processability, and
flexible physical properties are versatile in various applications. In recent years, the precise …
flexible physical properties are versatile in various applications. In recent years, the precise …
Discrete and stereospecific oligomers prepared by sequential and alternating single unit monomer insertion
Z Huang, BB Noble, N Corrigan, Y Chu… - Journal of the …, 2018 - ACS Publications
Natural biopolymers, such as DNA and proteins, have uniform microstructures with defined
molecular weight, precise monomer sequence, and stereoregularity along the polymer main …
molecular weight, precise monomer sequence, and stereoregularity along the polymer main …
A versatile and efficient strategy to discrete conjugated oligomers
J Lawrence, E Goto, JM Ren… - Journal of the …, 2017 - ACS Publications
An efficient and scalable strategy to prepare libraries of discrete conjugated oligomers (Đ=
1.0) using the combination of controlled polymerization and automated flash …
1.0) using the combination of controlled polymerization and automated flash …
Sequence-controlled polymers through entropy-driven ring-opening metathesis polymerization: theory, molecular weight control, and monomer design
The bulk properties of a copolymer are directly affected by monomer sequence, yet efficient,
scalable, and controllable syntheses of sequenced copolymers remain a defining challenge …
scalable, and controllable syntheses of sequenced copolymers remain a defining challenge …
Charge transport in sequence-defined conjugated oligomers
A major challenge in synthetic polymers lies in understanding how primary monomer
sequence affects materials properties. In this work, we show that charge transport in single …
sequence affects materials properties. In this work, we show that charge transport in single …
Poly (arylenevinylene) s through Ring‐Opening Metathesis Polymerization of an Unsymmetrical Donor‐Acceptor Cyclophane
E Elacqua, M Gregor - Angewandte Chemie International …, 2019 - Wiley Online Library
Reported are well‐defined donor‐acceptor alternating copolymers prepared using ring‐
opening metathesis polymerization (ROMP). Unsymmetrical cyclophanedienes comprising …
opening metathesis polymerization (ROMP). Unsymmetrical cyclophanedienes comprising …
Synthetic Polymers with Finely Regulated Monomer Sequences: Properties and Emerging Applications
The design of synthetic polymers with controlled monomer sequences is an important
emerging trend in polymer science. This new field of research is bio‐inspired by sequence …
emerging trend in polymer science. This new field of research is bio‐inspired by sequence …