Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters -
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The quest for alternatives to cyclopentadienyl-based ligands has led to a recent renaissance
of N-centered donor ligands in various fields of organometallic and coordination chemistry …

The review summarizes advances in the chemistry of organo rare-earth complexes
containing bulky guanidinate and amidopyridinate ligands. The methods of synthesis …

The synthesis and ring-opening polymerization (ROP) capability of bis (phenolate) amine-
supported samarium borohydride and amide complexes are reported, together with a DFT …

The first cationic main group tetrahydroborate complexes are reported.[Ca (BH4)(THF)
5][BPh4] and the charge neutral (TptBu, Me) Ca (BH4)(THF) are initiators for the living ring …

Borohydride complexes of the rare earths have attracted increasing interest during the last
decade. This review aims to cover recent results over this period with respect to the …

In this paper, we report the preparation and characterization of a series of unsymmetrical
group 4 metal complexes based on ONNO salalen-type ligands. In these examples, the …

Reaction of K [HC (C (Me) NAr′) 2](Ar′= 2, 6-C6H3iPr2) with Mg (BH4) 2 afforded the
pseudo four-coordinate tetrahydroborate complex Mg {HC (C (Me) NAr′) 2}(BH4)(THF)(1) …

The synthesis of a series of divalent and trivalent β-diketiminate borohydrides [(dipp)
2NacNacLn (BH4)(THF) 2]((dipp) 2NacNac=(2, 6-C6H3 i Pr2) NC (Me) CHC (Me) N (2, 6 …

The synthesis and characterization of a series of new diamido-ether actinide (IV) alkoxide
complexes are reported. Addition of 2 equiv of LiO i Pr to [t BuNON] ThCl5Li3· DME ([t …